Technology Process of Benzoic acid (E)-(S)-1-((Z)-pent-2-enyl)-8-trimethylsilanyl-oct-2-ene-4,7-diynyl ester
There total 6 articles about Benzoic acid (E)-(S)-1-((Z)-pent-2-enyl)-8-trimethylsilanyl-oct-2-ene-4,7-diynyl ester which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
propylamine; copper(l) iodide;
tetrakis(triphenylphosphine) palladium(0);
In
benzene;
at 20 ℃;
DOI:10.1016/j.tetlet.2005.03.175
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 84 percent / Py*SO3; DMSO; Et3N / CH2Cl2 / 20 °C
2: CrCl2 / tetrahydrofuran / 20 °C
3: 50 percent / n-PrNH2; CuI / Pd(Ph3)4 / benzene / 20 °C
With
chromium dichloride; propylamine; copper(l) iodide; sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine;
tetrakis(triphenylphosphine) palladium(0);
In
tetrahydrofuran; dichloromethane; benzene;
1: Swern oxidation / 2: Takai olefination;
DOI:10.1016/j.tetlet.2005.03.175
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 94 percent / pyridine / 0 - 20 °C
2: 96 percent / H2 / Lindlar cat. / hexane
3: 85 percent / EtSH; AlCl3 / CH2Cl2 / -35 °C
4: 84 percent / Py*SO3; DMSO; Et3N / CH2Cl2 / 20 °C
5: CrCl2 / tetrahydrofuran / 20 °C
6: 50 percent / n-PrNH2; CuI / Pd(Ph3)4 / benzene / 20 °C
With
pyridine; chromium dichloride; propylamine; copper(l) iodide; aluminium trichloride; hydrogen; sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine; ethanethiol;
tetrakis(triphenylphosphine) palladium(0); Lindlar catalyst;
In
tetrahydrofuran; hexane; dichloromethane; benzene;
4: Swern oxidation / 5: Takai olefination;
DOI:10.1016/j.tetlet.2005.03.175
