[nickel(II)chloride(triphenylphosphane)(N-benzyl-N-methyldithiocarbamate)]

Base Information

Chemical Name:[nickel(II)chloride(triphenylphosphane)(N-benzyl-N-methyldithiocarbamate)]
CAS No.:1251468-61-7
Molecular Formula:C₂₇H₂₅ClNNiPS₂
Molecular Weight:552.751
Hs Code.:

Synonyms:[nickel(II)chloride(triphenylphosphane)(N-benzyl-N-methyldithiocarbamate)]

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Chemical Property of [nickel(II)chloride(triphenylphosphane)(N-benzyl-N-methyldithiocarbamate)]

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Technology Process of [nickel(II)chloride(triphenylphosphane)(N-benzyl-N-methyldithiocarbamate)]

There total 1 articles about [nickel(II)chloride(triphenylphosphane)(N-benzyl-N-methyldithiocarbamate)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 14264-16-5,53996-95-5,62075-39-2,39716-73-9
bis(triphenylphosphine)nickel(II) chloride

: 82421-74-7
[nickel(II)(N-benzyl-N-methyldithiocarbamate)2]

: 1251468-61-7
[nickel(II)chloride(triphenylphosphane)(N-benzyl-N-methyldithiocarbamate)]

Guidance literature:: In chloroform; NiCl2(PPh3)2 (1 mmol) and Ni(BzMedtc)2 (1mmol) suspended in CHCl3, stirred at room temp.; filtered, Et2O added, left to stand at room temp. for a few d, ppt. filtered off, washed with Et2O, dried at 40°C under IR lamp; elem. anal.;
DOI:10.1002/zaac.201000091

Reference yield: 69.0%

: 1251468-61-7
[nickel(II)chloride(triphenylphosphane)(N-benzyl-N-methyldithiocarbamate)]

: 143-66-8
sodium tetraphenyl borate

: 603-35-0
triphenylphosphine

: 1251468-67-3
[nickel(II)(triphenylphosphane)2(N-benzyl-N-methyldithiocarbamate)]BPh₄

Guidance literature:: In methanol; Na(BPh4) (2 mmol) added to suspn. of Ni complex (1 mmol) and PPh3 (2 mmol), heated under reflux for 3 h; filtered, left to stand at room temp. for a few d, ppt. filtered off, washed with MeOH and Et2O, dried at 40°C under IR lamp; elem. anal.;
DOI:10.1002/zaac.201000091

Reference yield: 54.0%

: 17084-13-8
potassium hexafluorophosphate

: 1251468-61-7
[nickel(II)chloride(triphenylphosphane)(N-benzyl-N-methyldithiocarbamate)]

: 603-35-0
triphenylphosphine

: 1251468-68-4
[nickel(II)(triphenylphosphane)2(N-benzyl-N-methyldithiocarbamate)]PF₆

Guidance literature:: In chloroform; acetone; solns. of PPh3 (2 mmol) and KPF6 (1 mmol) (acetone) separetly addedd to soln. of Ni complex (1 mmol) (CHCl3), heated under reflux for 4 h; filtered, Et2O added, ppt. filtered off, washed with Et2O, dried at 40°C under IR lamp; elem. anal.;
DOI:10.1002/zaac.201000091