Carbon monoxide;1,10-phenanthroline;tungsten

Base Information

Chemical Name:Carbon monoxide;1,10-phenanthroline;tungsten
CAS No.:14729-20-5
Molecular Formula:C₁₆H₈N₂O₄W
Molecular Weight:476.101
Hs Code.:
NSC Number:132308

Synonyms:NSC132308;14729-20-5;NSC-132308

Suppliers and Price of Carbon monoxide;1,10-phenanthroline;tungsten

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of Carbon monoxide;1,10-phenanthroline;tungsten

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:0
Exact Mass:475.999340
Heavy Atom Count:23
Complexity:343

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.[W]

Technology Process of Carbon monoxide;1,10-phenanthroline;tungsten

There total 6 articles about Carbon monoxide;1,10-phenanthroline;tungsten which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 66-71-7
1,10-Phenanthroline

: disodium dichlorobis(pentacarbonyltungsten)stannate(II)

: 14040-11-0
tungsten hexacarbonyl

: 209454-47-7
bis(pentacarbonyltungsten)(1,10-phenanthroline)tin

: 14729-20-5
tetracarbonyl(1,10-phenanthroline)tungsten⁽⁰⁾

Guidance literature:: In tetrahydrofuran; byproducts: NaCl; Ar atmosphere, addn. of solid ligand to THF soln. of metal complex at 20°C, stirring (20°C, 30 min); removement of solvent (vacuum), dissolution (THF), chromy. (silica gel, elution of byproducts with Et2O, elution of main product with THF), evapn. to dryness; elem. anal.;
DOI:10.1002/(SICI)1099-0682(199806)1998:6<703::AID-EJIC703>3.0.CO;2-H

Reference yield:

: 36477-75-5
tungsten pentacarbonyl tetrahydrofuran

: 125932-20-9
fac-W(CO)3(1,10-phenanthroline)(acetonitrile)

: 14040-11-0
tungsten hexacarbonyl

: 14729-20-5
tetracarbonyl(1,10-phenanthroline)tungsten⁽⁰⁾

: [W(CO)3(1,10-phenanthroline)W(CO)5]

Guidance literature:: In tetrahydrofuran; under N2; W-phenanthroline complex dissolved in THF; cooled in ice bath (0-5°C); soln. of W(CO)5(THF) in THF added dropwise; 4 h; evapd. to small vol.; n-hexane added; detd. by IR spectroscopy;
DOI:10.1021/om030247f

Reference yield:

: 618381-64-9
[(CO)3(1,10-phenanthroline)W-cis-Ir(CO)2Cl]

: 603-35-0
triphenylphosphine

: 15318-31-7,14871-41-1,59246-46-7
bis(triphenylphosphine)iridium(I) carbonyl chloride

: 14729-20-5
tetracarbonyl(1,10-phenanthroline)tungsten⁽⁰⁾

Guidance literature:: In tetrahydrofuran; under N2; soln. of PPh3 (2 equiv.) in THF added to soln. of W-Ir complexin THF; not isolated; detd. by IR spectroscopy;
DOI:10.1021/om030247f