<(1S)-(1,2,4/3,5)-2-amino-3,4-dihydroxy-5-hydroxymethyl-1-cyclohexyl> α-D-mannopyranoside

Base Information

Chemical Name:<(1S)-(1,2,4/3,5)-2-amino-3,4-dihydroxy-5-hydroxymethyl-1-cyclohexyl> α-D-mannopyranoside
CAS No.:116163-49-6
Molecular Formula:C₁₃H₂₅NO₉
Molecular Weight:339.343
Hs Code.:

Synonyms:<(1S)-(1,2,4/3,5)-2-amino-3,4-dihydroxy-5-hydroxymethyl-1-cyclohexyl> α-D-mannopyranoside

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Chemical Property of <(1S)-(1,2,4/3,5)-2-amino-3,4-dihydroxy-5-hydroxymethyl-1-cyclohexyl> α-D-mannopyranoside

Chemical Property:

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Technology Process of <(1S)-(1,2,4/3,5)-2-amino-3,4-dihydroxy-5-hydroxymethyl-1-cyclohexyl> α-D-mannopyranoside

There total 13 articles about <(1S)-(1,2,4/3,5)-2-amino-3,4-dihydroxy-5-hydroxymethyl-1-cyclohexyl> α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 101924-32-7,101978-70-5,116183-94-9,116183-95-0,131063-66-6,131063-76-8
<(1S)-(1,2,4/3,5)-2-acetamido-3,4-dihydroxy-5-hydroxymethyl-1-cyclohexyl>α-D-mannopyranoside hepta-acetate

: 116163-49-6
<(1S)-(1,2,4/3,5)-2-amino-3,4-dihydroxy-5-hydroxymethyl-1-cyclohexyl> α-D-mannopyranoside

Guidance literature:: With hydrazine hydrate; In water; at 70 ℃; for 0.5h;
DOI:10.1016/0008-6215(87)85010-3

Reference yield: 58.0%

: 116163-49-6
<(1S)-(1,2,4/3,5)-2-amino-3,4-dihydroxy-5-hydroxymethyl-1-cyclohexyl> α-D-mannopyranoside

: 116163-49-6,116258-18-5,131063-65-5,131063-67-7,131063-72-4,131063-75-7
<(1R)-(1,2,4/3,5)-2-amino-3,4-dihydroxy-5-hydroxymethyl-1-cyclohexyl> α-D-mannopyranoside

Guidance literature:: With hydrazine hydrate; In water; at 70 ℃; for 0.5h;
DOI:10.1016/0008-6215(87)85010-3

Reference yield:

: 14218-11-2,14218-30-5,61198-88-7,108438-33-1,108836-02-8,114682-36-9,127305-34-4,151377-77-4
2,3,4,6-Tetra-O-benzoyl-α-D-mannopyranosyl bromide

: 116163-49-6,116258-18-5,131063-65-5,131063-67-7,131063-72-4,131063-75-7
<(1R)-(1,2,4/3,5)-2-amino-3,4-dihydroxy-5-hydroxymethyl-1-cyclohexyl> α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 84 percent / mercury(II) cyanide, Drierite / benzene / 64 h / Heating

2: 64 percent / sodium acetate / dimethylformamide / 15 h / 80 °C

3: 1.) sodium methoxide, 2.) pyridine / 1.) methanol, room temp., 2 h; 2.) room temp.

4: pyridine

5: 58 percent / hydrazine hydrate / H₂O / 0.5 h / 70 °C

6: 58 percent / hydrazine hydrate / H₂O / 0.5 h / 70 °C

With pyridine; calcium sulfate; sodium methylate; sodium acetate; mercury(II) cyanide; hydrazine hydrate; In water; N,N-dimethyl-formamide; benzene;
DOI:10.1016/0008-6215(87)85010-3