(11S,15S)-16-methylidene-10-(3,4,5-trimethoxyphenyl)-4,6,13-trioxatetracyclo[7.7.0.0^{^}{3,7}.0^{^}{11,15}]hexadeca-1,3⁽⁷⁾,8-trien-12-one

Base Information

• Chemical Name: (11S,15S)-16-methylidene-10-(3,4,5-trimethoxyphenyl)-4,6,13-trioxatetracyclo[7.7.0.0^{^}{3,7}.0^{^}{11,15}]hexadeca-1,3⁽⁷⁾,8-trien-12-one
• CAS No.: 1132041-56-5
• Molecular Formula: C₂₃H₂₂O₇
• Molecular Weight: 410.423

Synonyms:(11S,15S)-16-methylidene-10-(3,4,5-trimethoxyphenyl)-4,6,13-trioxatetracyclo[7.7.0.0^{^}{3,7}.0^{^}{11,15}]hexadeca-1,3⁽⁷⁾,8-trien-12-one

Chemical Property of (11S,15S)-16-methylidene-10-(3,4,5-trimethoxyphenyl)-4,6,13-trioxatetracyclo[7.7.0.0^{^}{3,7}.0^{^}{11,15}]hexadeca-1,3⁽⁷⁾,8-trien-12-one

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Technology Process of (11S,15S)-16-methylidene-10-(3,4,5-trimethoxyphenyl)-4,6,13-trioxatetracyclo[7.7.0.0^{^}{3,7}.0^{^}{11,15}]hexadeca-1,3⁽⁷⁾,8-trien-12-one

There total 1 articles about (11S,15S)-16-methylidene-10-(3,4,5-trimethoxyphenyl)-4,6,13-trioxatetracyclo[7.7.0.0^{^}{3,7}.0^{^}{11,15}]hexadeca-1,3⁽⁷⁾,8-trien-12-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

6-{[(4R)-4-ethenyl-2-oxooxolan-3-yl](3,4,5-trimethoxyphenyl)methyl}-2H-1,3-benzodioxol-5-yl trifluoromethanesulfonate (1083302-72-0) → (11S,15S)-16-methylidene-10-(3,4,5-trimethoxyphenyl)-4,6,13-trioxatetracyclo[7.7.0.0^{3,7}.0^{11,15}]hexadeca-1,3(7),8-trien-12-one (1132041-56-5)

Guidance literature:

With sodium carbonate; trans-di(μ-acetato)-bis[o-(di-o-tolylphosphino)benzyl]-dipalladium(II); In ethanol; for 15h; Product distribution / selectivity; Reflux;

Reference yield: 90.0%

(11S,15S)-16-methylidene-10-(3,4,5-trimethoxyphenyl)-4,6,13-trioxatetracyclo[7.7.0.0^{3,7}.0^{11,15}]hexadeca-1,3(7),8-trien-12-one (1132041-56-5) → (5aR,8aS,9R)-9-(3,4,5-trimethoxyphenyl)-5a,6,8a,9-tetrahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxole-5,8-dione (477-48-5)

Guidance literature:

(11S,15S)-16-methylidene-10-(3,4,5-trimethoxyphenyl)-4,6,13-trioxatetracyclo[7.7.0.0^{^}{3,7}.0^{^}{11,15}]hexadeca-1,3⁽⁷⁾,8-trien-12-one; With osmium(VIII) oxide; 4-methylmorpholine N-oxide; In dichloromethane; water; at 20 ℃; for 4h;

With sodium periodate; at 20 ℃; for 1h; Product distribution / selectivity;

upstream raw materials:

6-{[(4R)-4-ethenyl-2-oxooxolan-3-yl](3,4,5-trimethoxyphenyl)methyl}-2H-1,3-benzodioxol-5-yl trifluoromethanesulfonate

Downstream raw materials:

(5aR,8aS,9R)-9-(3,4,5-trimethoxyphenyl)-5a,6,8a,9-tetrahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxole-5,8-dione

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