(E)-(5-chloropent-1-en-1-yl)(o-tolyl)-λ³-iodanyl trifluoromethanesulfonate

Base Information

Chemical Name:(E)-(5-chloropent-1-en-1-yl)(o-tolyl)-λ³-iodanyl trifluoromethanesulfonate
CAS No.:1428541-20-1
Molecular Formula:C₁₃H₁₅ClF₃IO₃S
Molecular Weight:470.679
Hs Code.:

(E)-(5-chloropent-1-en-1-yl)(o-tolyl)-λ<sup>3</sup>-iodanyl trifluoromethanesulfonate

Synonyms:(E)-(5-chloropent-1-en-1-yl)(o-tolyl)-λ³-iodanyl trifluoromethanesulfonate

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Chemical Property of (E)-(5-chloropent-1-en-1-yl)(o-tolyl)-λ³-iodanyl trifluoromethanesulfonate

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Technology Process of (E)-(5-chloropent-1-en-1-yl)(o-tolyl)-λ³-iodanyl trifluoromethanesulfonate

There total 3 articles about (E)-(5-chloropent-1-en-1-yl)(o-tolyl)-λ³-iodanyl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1493-13-6
trifluorormethanesulfonic acid

: 31599-59-4
2-(diacetoxyiodo)toluene

: 37490-32-7
[(1E)-5-chloropent-1-en-1-yl]boronic acid

: 1428541-20-1
(E)-(5-chloropent-1-en-1-yl)(o-tolyl)-λ³-iodanyl trifluoromethanesulfonate

Guidance literature:: [(1E)-5-chloropent-1-en-1-yl]boronic acid; With boron trifluoride diethyl etherate; In dichloromethane; at 0 ℃; for 0.25h; Inert atmosphere;

2-(diacetoxyiodo)toluene; In dichloromethane; at 0 ℃; for 1h; Inert atmosphere;

trifluorormethanesulfonic acid; In dichloromethane; at 0 ℃; for 0.25h;
DOI:10.1021/ja401840j

Reference yield:

: 615-37-2
ortho-methylphenyl iodide

: 1428541-20-1
(E)-(5-chloropent-1-en-1-yl)(o-tolyl)-λ³-iodanyl trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium peroxoborate tetrahydrate / 45 °C / Inert atmosphere

2.1: boron trifluoride diethyl etherate / dichloromethane / 0.25 h / 0 °C / Inert atmosphere

2.2: 1 h / 0 °C / Inert atmosphere

2.3: 0.25 h / 0 °C

With sodium peroxoborate tetrahydrate; boron trifluoride diethyl etherate; In dichloromethane;
DOI:10.1021/ja401840j

Reference yield:

: 126688-98-0
B-2-(E)-(5-chloropent-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 1428541-20-1
(E)-(5-chloropent-1-en-1-yl)(o-tolyl)-λ³-iodanyl trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1.1: ammonium acetate; sodium periodate / acetone / 24 h / 20 °C / Inert atmosphere

2.1: boron trifluoride diethyl etherate / dichloromethane / 0.25 h / 0 °C / Inert atmosphere

2.2: 1 h / 0 °C / Inert atmosphere

2.3: 0.25 h / 0 °C

With sodium periodate; boron trifluoride diethyl etherate; ammonium acetate; In dichloromethane; acetone;
DOI:10.1021/ja401840j