C₂₉H₄₂O₆SSi

Base Information

Chemical Name:C₂₉H₄₂O₆SSi
CAS No.:1592771-68-0
Molecular Formula:C₂₉H₄₂O₆SSi
Molecular Weight:546.8
Hs Code.:

C<sub>29</sub>H<sub>42</sub>O<sub>6</sub>SSi

Synonyms:C₂₉H₄₂O₆SSi

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Chemical Property of C₂₉H₄₂O₆SSi

Chemical Property:

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Technology Process of C₂₉H₄₂O₆SSi

There total 16 articles about C₂₉H₄₂O₆SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1592771-11-3
C₂₉H₄₂O₅SSi

: 1592771-13-5
C₂₉H₄₂O₆SSi

: 1592771-68-0
C₂₉H₄₂O₆SSi

Guidance literature:: With tert.-butylhydroperoxide; potassium tert-butylate; In tetrahydrofuran; at -80 - -25 ℃; for 16h; Overall yield = 77 %; Overall yield = 3.90 g; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/ol500788c

Reference yield:

: methyl 3-O-benzyl-5-O-(p-toluenesulfonyl)-2-deoxy-D-ribofuranoside

: 1592771-13-5
C₂₉H₄₂O₆SSi

: 1592771-68-0
C₂₉H₄₂O₆SSi

Guidance literature:: Multi-step reaction with 12 steps

1: lithium triethylborohydride / tetrahydrofuran / 6.25 h / 20 - 45 °C / Inert atmosphere

2: boron trifluoride diethyl etherate / dichloromethane / 0.67 h / 0 - 20 °C / Inert atmosphere

3: 4-methyl-morpholine / dichloromethane / 2 h / 20 °C / Inert atmosphere

4: methyl iodide; sodium hydrogencarbonate / acetonitrile; water / 24 h / 20 °C

5: samarium diiodide / acetonitrile; methanol / 1 h / -20 °C / Inert atmosphere

6: Dess-Martin periodane / dichloromethane / 1.5 h / 20 °C / Inert atmosphere

7: sodium tetrahydroborate / dichloromethane; methanol / 0.5 h / -80 °C / Inert atmosphere

8: 2,6-dimethylpyridine / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

9: potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.5 h / 0 °C / Inert atmosphere

10: diisobutylaluminium hydride / dichloromethane; hexane / 0.75 h / -80 °C / Inert atmosphere

11: lithium chloride; triethylamine / acetonitrile / 5 h / 20 °C / Inert atmosphere

12: potassium tert-butylate; tert.-butylhydroperoxide / tetrahydrofuran / 16 h / -80 - -25 °C / Inert atmosphere

With 4-methyl-morpholine; 2,6-dimethylpyridine; tert.-butylhydroperoxide; sodium tetrahydroborate; samarium diiodide; boron trifluoride diethyl etherate; potassium tert-butylate; potassium hexamethylsilazane; diisobutylaluminium hydride; lithium triethylborohydride; sodium hydrogencarbonate; Dess-Martin periodane; triethylamine; lithium chloride; methyl iodide; In tetrahydrofuran; methanol; hexane; dichloromethane; water; toluene; acetonitrile; 6: |Dess-Martin Oxidation / 11: |Horner-Wadsworth-Emmons Olefination;
DOI:10.1021/ol500788c

Reference yield:

: methyl 3-O-benzyl-2,5-dideoxy-D-erythropentofuranoside

: 1592771-13-5
C₂₉H₄₂O₆SSi

: 1592771-68-0
C₂₉H₄₂O₆SSi

Guidance literature:: Multi-step reaction with 11 steps

1: boron trifluoride diethyl etherate / dichloromethane / 0.67 h / 0 - 20 °C / Inert atmosphere

2: 4-methyl-morpholine / dichloromethane / 2 h / 20 °C / Inert atmosphere

3: methyl iodide; sodium hydrogencarbonate / acetonitrile; water / 24 h / 20 °C

4: samarium diiodide / acetonitrile; methanol / 1 h / -20 °C / Inert atmosphere

5: Dess-Martin periodane / dichloromethane / 1.5 h / 20 °C / Inert atmosphere

6: sodium tetrahydroborate / dichloromethane; methanol / 0.5 h / -80 °C / Inert atmosphere

7: 2,6-dimethylpyridine / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

8: potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.5 h / 0 °C / Inert atmosphere

9: diisobutylaluminium hydride / dichloromethane; hexane / 0.75 h / -80 °C / Inert atmosphere

10: lithium chloride; triethylamine / acetonitrile / 5 h / 20 °C / Inert atmosphere

11: potassium tert-butylate; tert.-butylhydroperoxide / tetrahydrofuran / 16 h / -80 - -25 °C / Inert atmosphere

With 4-methyl-morpholine; 2,6-dimethylpyridine; tert.-butylhydroperoxide; sodium tetrahydroborate; samarium diiodide; boron trifluoride diethyl etherate; potassium tert-butylate; potassium hexamethylsilazane; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; triethylamine; lithium chloride; methyl iodide; In tetrahydrofuran; methanol; hexane; dichloromethane; water; toluene; acetonitrile; 5: |Dess-Martin Oxidation / 10: |Horner-Wadsworth-Emmons Olefination;
DOI:10.1021/ol500788c