rhodium(8-hydroxyquinolate)(carbonyl)(2-bromo-3,4,5,6-tetrafluorophenyldiphenylphosphine)

Base Information

Chemical Name:rhodium(8-hydroxyquinolate)(carbonyl)(2-bromo-3,4,5,6-tetrafluorophenyldiphenylphosphine)
CAS No.:92951-84-3
Molecular Formula:C₂₈H₁₆BrF₄NO₂PRh
Molecular Weight:688.217
Hs Code.:

Synonyms:rhodium(8-hydroxyquinolate)(carbonyl)(2-bromo-3,4,5,6-tetrafluorophenyldiphenylphosphine)

Suppliers and Price of rhodium(8-hydroxyquinolate)(carbonyl)(2-bromo-3,4,5,6-tetrafluorophenyldiphenylphosphine)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of rhodium(8-hydroxyquinolate)(carbonyl)(2-bromo-3,4,5,6-tetrafluorophenyldiphenylphosphine)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of rhodium(8-hydroxyquinolate)(carbonyl)(2-bromo-3,4,5,6-tetrafluorophenyldiphenylphosphine)

There total 1 articles about rhodium(8-hydroxyquinolate)(carbonyl)(2-bromo-3,4,5,6-tetrafluorophenyldiphenylphosphine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: acetylacetonatodicarbonylrhodium(l)

: 148-24-3,24804-14-6
8-quinolinol

: 27384-33-4
(2-bromo-3,4,5,6-tetrafluorophenyl)diphenylphosphine

: 92951-84-3
rhodium(8-hydroxyquinolate)(carbonyl)(2-bromo-3,4,5,6-tetrafluorophenyldiphenylphosphine)

Guidance literature:: In dichloromethane; byproducts: CO; after stirring for 90 min the phosphine is added;; monitored by IR, solvent partly removed in vac., hexane was added, elem. anal.;
DOI:10.1016/0022-328X(84)80382-4

Reference yield: 87.0%

: 92951-84-3
rhodium(8-hydroxyquinolate)(carbonyl)(2-bromo-3,4,5,6-tetrafluorophenyldiphenylphosphine)

: Rh(C₉H₆N(O))Br(P(C₆H₅)2(C₆F₄))(H₂O)

Guidance literature:: With Et₄NBr; In toluene; under Ar; adding Et4NBr to a soln. of the complex, refluxing the suspn.(15 h), color changing from orange to red, pptn.; filtering, washing (toluene), extg. from a CH2Cl2 soln. (H2O), drying the organic phase (Na2SO4), concg. (reduced pressure), adding hexane; elem. anal.;
DOI:10.1016/S0022-328X(00)99585-8

Reference yield:

: 92951-84-3
rhodium(8-hydroxyquinolate)(carbonyl)(2-bromo-3,4,5,6-tetrafluorophenyldiphenylphosphine)

: 34431-14-6,20102-32-3
carbonyl(triphenylphosphine)(oxinato)rhodium(I)

Guidance literature:: With triphenylphosphine; In toluene; byproducts: 2-bromo-3,4,5,6-tetrafluorophenyldiphenylphosphine; phosphine was added in stoichiometric ratio under N2;
DOI:10.1016/0022-328X(84)80382-4