3-methylbenzenesulfonyl azide

Base Information

• Chemical Name: 3-methylbenzenesulfonyl azide
• CAS No.: 13222-18-9
• Molecular Formula: C₇H₇N₃O₂S
• Molecular Weight: 197.217
• Mol file: 13222-18-9.mol

Synonyms:3-methylbenzenesulfonyl azide

Chemical Property of 3-methylbenzenesulfonyl azide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of 3-methylbenzenesulfonyl azide

There total 2 articles about 3-methylbenzenesulfonyl azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

3-methylbenzenesulfonamide (1899-94-1) → 3-methylbenzenesulfonyl azide (13222-18-9)

Guidance literature:

With 3-azidosulfonyl-3H-imidazole-1-ium hydrogen sulfate; potassium carbonate; In water; isopropyl alcohol; at 20 ℃; for 18h;

DOI:10.1021/jo500553q

Reference yield:

3-methylphenylsulfonyl chloride (1899-93-0) → 3-methylbenzenesulfonyl azide (13222-18-9)

Guidance literature:

With sodium azide; In water; acetone; at 0 - 20 ℃; for 12h;

DOI:10.1016/j.cclet.2015.08.009

Reference yield: 97.0%

3-phenylbenzo[d]isothiazole-1,1-dioxide (53440-57-6) + 3-methylbenzenesulfonyl azide (13222-18-9) → N-(2-(1,1-dioxidobenzo[d]isothiazol-3-yl)phenyl)-3-methylbenzenesulfonamide

Guidance literature:

With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; silver(I) triflimide; In 2,2,2-trifluoroethanol; at 80 ℃; for 2h; chemoselective reaction;

DOI:10.1002/adsc.201700785

upstream raw materials:

3-methylbenzenesulfonamide

3-methylphenylsulfonyl chloride

Downstream raw materials:

3-methyldiphenylsulphone