[RuCl(4-(3,5-di-tert-butyl)phenyl-2,2':6',2''-terpyridine)(1,10-phenathroline)][PF₆]

Base Information

• Chemical Name: [RuCl(4-(3,5-di-tert-butyl)phenyl-2,2':6',2''-terpyridine)(1,10-phenathroline)][PF₆]
• CAS No.: 660860-66-2
• Molecular Formula: C₄₁H₃₉ClN₅Ru*F₆P
• Molecular Weight: 883.281

Synonyms:[RuCl(4-(3,5-di-tert-butyl)phenyl-2,2':6',2''-terpyridine)(1,10-phenathroline)][PF₆]

Chemical Property of [RuCl(4-(3,5-di-tert-butyl)phenyl-2,2':6',2''-terpyridine)(1,10-phenathroline)][PF₆]

Chemical Property:

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Technology Process of [RuCl(4-(3,5-di-tert-butyl)phenyl-2,2':6',2''-terpyridine)(1,10-phenathroline)][PF₆]

There total 1 articles about [RuCl(4-(3,5-di-tert-butyl)phenyl-2,2':6',2''-terpyridine)(1,10-phenathroline)][PF₆] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

potassium hexafluorophosphate (17084-13-8) + Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl3 (660860-77-5) + 1,10-phenanthroline hydrate (5144-89-8) + lithium chloride → [RuCl(4-(3,5-di-tert-butyl)phenyl-2,2':6',2''-terpyridine)(1,10-phenathroline)][PF6] (660860-66-2)

Guidance literature:

With triethylamine; In ethanol; water; Ru complex, monoaqua-1,10-phenanthroline, LiCl, Et3N heated to reflux inEtOH-H2O for 4 h under Ar; soln. of satd. aq. KPF6 added; EtOH evapd.; ppt. filtered; washed (H2O, ether); column chromd. on SiO2 (Me2CO-H2O-satd. KNO3 (aq.), 100:5:0.1 as eluent); Et2O diffused into acetone soln.;

DOI:10.1039/b310198c

Reference yield: 100.0%

potassium hexafluorophosphate (17084-13-8) + [RuCl(4-(3,5-di-tert-butyl)phenyl-2,2':6',2''-terpyridine)(1,10-phenathroline)][PF6] (660860-66-2) + acetonitrile (75-05-8,26809-02-9) → [Ru(4'-(3,5-ditertiobutyl)phenyl-2,2',6'2''-terpyridine)(1,10-phenanthroline)(CH3CN)](PF6)2

Guidance literature:

With AgBF₄; In water; acetonitrile; byproducts: AgCl; Ru complex and AgBF4 dissolved in mixt. of H2O-MeCN; soln. heated to reflux under Ar atm. for 4.5 h; AgCl filtered over Celite; vol. of MeCN wasreduced by evapn.; satd. aq. soln. of KPF6 added; MeCN evapd.; filtered; washed (H2O); dried (vac.);

DOI:10.1039/b310198c

Reference yield: 69.0%

potassium hexafluorophosphate (17084-13-8) + [RuCl(4-(3,5-di-tert-butyl)phenyl-2,2':6',2''-terpyridine)(1,10-phenathroline)][PF6] (660860-66-2) + water (7732-18-5) → [Ru(4'-(3,5-ditertiobutyl)phenyl-2,2',6'2''-terpyridine)(1,10-phenanthroline)(H2O)](PF6)2

Guidance literature:

With AgBF₄; In water; acetone; byproducts: AgCl; Ru complex and AgBF4 dissolved in mixt. of H2O-Me2CO; soln. degassed andheated to reflux under Ar atm. for 3 h; AgCl filtered over Celite; H2O and aq. soln. of KPF6 added; Me2CO evapd.; filtered; washed (H2O);

DOI:10.1039/b310198c

upstream raw materials:

potassium hexafluorophosphate

Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl₃

1,10-phenanthroline hydrate

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