C₁₀H₉BrO

Base Information

• Chemical Name: C₁₀H₉BrO
• CAS No.: 1261038-30-5
• Molecular Formula: C₁₀H₉BrO
• Molecular Weight: 225.085
• Mol file: 1261038-30-5.mol

Synonyms:C₁₀H₉BrO

Chemical Property of C₁₀H₉BrO

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of C₁₀H₉BrO

There total 2 articles about C₁₀H₉BrO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

1-bromo-4-(cyclopropylidenemethyl)benzene (179251-27-5) → C10H9BrO (1261038-30-5)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 1h; Inert atmosphere;

DOI:10.1021/acs.orglett.7b03707

Reference yield:

4-bromo-benzaldehyde (1122-91-4) → C10H9BrO (1261038-30-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: potassium tert-butylate / tetrahydrofuran / 1 h / 70 °C / Inert atmosphere

1.2: Inert atmosphere; Reflux

2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 0 °C / Inert atmosphere

With potassium tert-butylate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;

DOI:10.1021/acs.orglett.7b03707

Reference yield: 98.0%

C10H9BrO (1261038-30-5) → C10H10BrNO

Guidance literature:

With hydroxylamine hydrochloride; sodium acetate; In methanol; at 75 ℃; for 12h; Inert atmosphere;

DOI:10.1021/acs.orglett.7b03707

upstream raw materials:

1-bromo-4-(cyclopropylidenemethyl)benzene

4-bromo-benzaldehyde