10-Hydroxy-decanoic acid (3E,5E,7E)-7-methyl-9-oxo-3-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-nona-3,5,7-trienyl ester

Base Information

Chemical Name:10-Hydroxy-decanoic acid (3E,5E,7E)-7-methyl-9-oxo-3-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-nona-3,5,7-trienyl ester
CAS No.:121846-29-5
Molecular Formula:C₃₁H₄₈O₄
Molecular Weight:484.72
Hs Code.:

Synonyms:10-Hydroxy-decanoic acid (3E,5E,7E)-7-methyl-9-oxo-3-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-nona-3,5,7-trienyl ester

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Chemical Property of 10-Hydroxy-decanoic acid (3E,5E,7E)-7-methyl-9-oxo-3-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-nona-3,5,7-trienyl ester

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Technology Process of 10-Hydroxy-decanoic acid (3E,5E,7E)-7-methyl-9-oxo-3-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-nona-3,5,7-trienyl ester

There total 5 articles about 10-Hydroxy-decanoic acid (3E,5E,7E)-7-methyl-9-oxo-3-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-nona-3,5,7-trienyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 121846-23-9
(E)-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenal S,S-acetal

: 121846-29-5
10-Hydroxy-decanoic acid (3E,5E,7E)-7-methyl-9-oxo-3-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-nona-3,5,7-trienyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 44 percent / n-BuLi / tetrahydrofuran / -78 °C

2: 1.) HgCl₂, HgO, 2.) Et₃N / 1.) 95percent aq. MeOH, reflux, 2.) CH₂Cl₂

3: 1.) NaH, 2.) DIBAL / 1.) THF, 2.) Et₂O, -78 deg C

5: 1.) DCC, DMAP, 2.) n-Bu₄NF / 1.) CH₂Cl₂, 2.) THF

With dmap; n-butyllithium; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; triethylamine; dicyclohexyl-carbodiimide; mercury dichloride; mercury(II) oxide; In tetrahydrofuran;
DOI:10.1021/ja00195a073

Reference yield:

: (E)-5-(tert-Butyl-dimethyl-silanyloxy)-1-(2,6,6-trimethyl-cyclohex-1-enyl)-pent-1-en-3-one

: 121846-29-5
10-Hydroxy-decanoic acid (3E,5E,7E)-7-methyl-9-oxo-3-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-nona-3,5,7-trienyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) NaH, 2.) DIBAL / 1.) THF, 2.) Et₂O, -78 deg C

3: 1.) DCC, DMAP, 2.) n-Bu₄NF / 1.) CH₂Cl₂, 2.) THF

With dmap; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; dicyclohexyl-carbodiimide;
DOI:10.1021/ja00195a073

Reference yield:

: 121846-25-1
(2E,4E)-3-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienal

: 121846-29-5
10-Hydroxy-decanoic acid (3E,5E,7E)-7-methyl-9-oxo-3-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-nona-3,5,7-trienyl ester

Guidance literature:: Multi-step reaction with 2 steps

2: 1.) DCC, DMAP, 2.) n-Bu₄NF / 1.) CH₂Cl₂, 2.) THF

With dmap; tetrabutyl ammonium fluoride; dicyclohexyl-carbodiimide;
DOI:10.1021/ja00195a073