(Z)-(2S,4R,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-yl 5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoate

Base Information

Chemical Name:(Z)-(2S,4R,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-yl 5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoate
CAS No.:1394247-82-5
Molecular Formula:C₃₃H₅₀I₂O₅Si
Molecular Weight:808.651
Hs Code.:

(Z)-(2S,4R,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-yl 5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoate

Synonyms:(Z)-(2S,4R,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-yl 5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoate

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Chemical Property of (Z)-(2S,4R,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-yl 5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoate

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Technology Process of (Z)-(2S,4R,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-yl 5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoate

There total 7 articles about (Z)-(2S,4R,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-yl 5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1174549-23-5
(Z)-5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoic acid

: 1394247-88-1
(2S,4S,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-ol

: 1394247-82-5
(Z)-(2S,4R,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-yl 5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoate

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In benzene; at 0 - 20 ℃; for 1.5h;
DOI:10.1021/ol302219x

Reference yield: 51.0%

: 1174549-23-5
(Z)-5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoic acid

: 1394247-78-9
(2S,4R,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-ol

: 1394247-86-9
C₃₃H₅₁IO₆Si

: 1394247-82-5
(Z)-(2S,4R,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-yl 5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoate

: 1394247-84-7
C₃₃H₄₉IO₅Si

Guidance literature:: (Z)-5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoic acid; With 2,4,6-trichlorobenzoyl chloride; triethylamine; In toluene; at 0 ℃; for 2h;

(2S,4R,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-ol; With dmap; In toluene; at 0 ℃;
DOI:10.1021/ol302219x

Reference yield:

: 1174549-23-5
(Z)-5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoic acid

: 1394247-78-9
(2S,4R,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-ol

: 1394247-82-5
(Z)-(2S,4R,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-yl 5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoate

Guidance literature:: (Z)-5-((tert-butyldimethylsilyl)oxy)-3-iodopent-2-enoic acid; With 1-chloro-1-(dimethylamino)-2-methyl-1-propene;

(2S,4R,6R)-6-((E)-3-iodo-2-methylallyl)-2-methoxy-2-((E)-3-methyl-5-phenylpent-3-en-1-yl)tetrahydro-2H-pyran-4-ol; With sodium hexamethyldisilazane; In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1021/ol302219x