methyl 2,3,6-tri-O-benzyl-4-O-(4,6-O-benzylidene-2-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-β-D-glucopyranosyl)-β-D-galactopyranoside

Base Information

Chemical Name:methyl 2,3,6-tri-O-benzyl-4-O-(4,6-O-benzylidene-2-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-β-D-glucopyranosyl)-β-D-galactopyranoside
CAS No.:866229-73-4
Molecular Formula:C₇₅H₇₂O₂₀
Molecular Weight:1293.38
Hs Code.:

Synonyms:methyl 2,3,6-tri-O-benzyl-4-O-(4,6-O-benzylidene-2-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-β-D-glucopyranosyl)-β-D-galactopyranoside

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Chemical Property of methyl 2,3,6-tri-O-benzyl-4-O-(4,6-O-benzylidene-2-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-β-D-glucopyranosyl)-β-D-galactopyranoside

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Technology Process of methyl 2,3,6-tri-O-benzyl-4-O-(4,6-O-benzylidene-2-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-β-D-glucopyranosyl)-β-D-galactopyranoside

There total 4 articles about methyl 2,3,6-tri-O-benzyl-4-O-(4,6-O-benzylidene-2-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-β-D-glucopyranosyl)-β-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 866229-72-3
methyl 2,3,6-tri-O-benzyl-4-O-(4,6-O-benzylidene-3-O-p-methoxybenzyl-β-D-glucopyranosyl)-β-D-galactopyranoside

: 149707-75-5
2,3,4,6-tetra-O-benzoyl-D-glucopyranosyl trichloroacetimidate

: 866229-73-4
methyl 2,3,6-tri-O-benzyl-4-O-(4,6-O-benzylidene-2-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-β-D-glucopyranosyl)-β-D-galactopyranoside

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; In dichloromethane; at 0 ℃; for 1h;
DOI:10.1039/b508752j

Reference yield:

: 866229-71-2
methyl 2,3,6-tri-O-benzyl-4-O-(4,6-O-benzylidene-2-O-benzoyl-3-O-p-methoxybenzyl-β-D-glucopyranosyl)-β-D-galactopyranoside

: 866229-73-4
methyl 2,3,6-tri-O-benzyl-4-O-(4,6-O-benzylidene-2-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-β-D-glucopyranosyl)-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / NaOMe / methanol / 30 h / 20 °C

2: 64 percent / 4 Angstroem molecular sieves; TMSOTf / CH₂Cl₂ / 1 h / 0 °C

With trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; sodium methylate; In methanol; dichloromethane;
DOI:10.1039/b508752j

Reference yield:

: 51842-16-1
methyl 2,3,6-tri-O-benzyl-β-D-galactopyranoside

: 866229-73-4
methyl 2,3,6-tri-O-benzyl-4-O-(4,6-O-benzylidene-2-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-β-D-glucopyranosyl)-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 62 percent / 4 Angstroem molecular sieves; TfOH; NIS / CH₂Cl₂ / 1 h / 0 °C

2: 87 percent / NaOMe / methanol / 30 h / 20 °C

3: 64 percent / 4 Angstroem molecular sieves; TMSOTf / CH₂Cl₂ / 1 h / 0 °C

With N-iodo-succinimide; trifluorormethanesulfonic acid; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; sodium methylate; In methanol; dichloromethane;
DOI:10.1039/b508752j