5,15-(di-3,5-di-tert-butylphenyl)porphyrinato nickel(II)

Base Information

• Chemical Name: 5,15-(di-3,5-di-tert-butylphenyl)porphyrinato nickel(II)
• CAS No.: 175444-05-0
• Molecular Formula: C₄₈H₅₂N₄Ni
• Molecular Weight: 743.658
• Mol file: 175444-05-0.mol

Synonyms:5,15-(di-3,5-di-tert-butylphenyl)porphyrinato nickel(II)

Chemical Property of 5,15-(di-3,5-di-tert-butylphenyl)porphyrinato nickel(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,15-(di-3,5-di-tert-butylphenyl)porphyrinato nickel(II)

There total 8 articles about 5,15-(di-3,5-di-tert-butylphenyl)porphyrinato nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

((C20H9N4)((C6H3)(CMe3)2)2(HgCl))Ni (945857-20-5) + trifluoroacetic acid (76-05-1) → (5,15-bis(3,5-di-tert-butylphenyl)porphyrinate)nickel(II) (175444-05-0)

Guidance literature:

With NaHCO₃; treated with CF3CO2H and then with aq. NaHCO3;

DOI:10.1039/b618464b

Reference yield: 98.0%

bis(acetylacetonate)nickel(II) + 5,15-di(3,5-di-tert-butylphenyl)-21H,23H-porphine → (5,15-bis(3,5-di-tert-butylphenyl)porphyrinate)nickel(II) (175444-05-0)

Guidance literature:

In toluene; mixt. of porphyrin and Ni compd. dissolved in toluene; refluxed for 3 h;monitored by TLC; solvent removed in vac.; passed through plug of silica gel (CHCl3); recrystd. from CHCl3-MeOH;

DOI:10.1039/b516989e

Reference yield: 97.0%

nickel(II) acetate tetrahydrate (6018-89-9) + 5,15-bis(3',5'-di-tert-butylphenyl)porphyrin → (5,15-bis(3,5-di-tert-butylphenyl)porphyrinate)nickel(II) (175444-05-0)

Guidance literature:

In N,N-dimethyl-formamide; at 140 ℃; for 10h;

DOI:10.1021/jacs.9b08584

upstream raw materials:

((C₂₀H₉N₄)((C₆H₃)(CMe₃)2)2(HgCl))Ni

trifluoroacetic acid

nickel(II) acetate tetrahydrate

5,15-bis(phenylethynyl)-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II)

Downstream raw materials:

5,15-dibromo-10,20-bis(3,5-di-tert-butylphenyl)porphyrinatonickel(II)