(E)-(tert-butyl) 2-((5-(tert-butyl)diphenylsilyloxy)-3-methylpent-1-en-3-yl)diazenecarboxylate

Base Information

Chemical Name:(E)-(tert-butyl) 2-((5-(tert-butyl)diphenylsilyloxy)-3-methylpent-1-en-3-yl)diazenecarboxylate
CAS No.:1332865-02-7
Molecular Formula:C₂₇H₃₈N₂O₃Si
Molecular Weight:466.696
Hs Code.:

Synonyms:(E)-(tert-butyl) 2-((5-(tert-butyl)diphenylsilyloxy)-3-methylpent-1-en-3-yl)diazenecarboxylate

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Chemical Property of (E)-(tert-butyl) 2-((5-(tert-butyl)diphenylsilyloxy)-3-methylpent-1-en-3-yl)diazenecarboxylate

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Technology Process of (E)-(tert-butyl) 2-((5-(tert-butyl)diphenylsilyloxy)-3-methylpent-1-en-3-yl)diazenecarboxylate

There total 5 articles about (E)-(tert-butyl) 2-((5-(tert-butyl)diphenylsilyloxy)-3-methylpent-1-en-3-yl)diazenecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 1332864-72-8
(E)-(tert-butyl) 1-(5-((tert-butyl)diphenylsilyloxy)-3-methylpent-2-enyl)hydrazinecarboxylate

: 1332865-02-7
(E)-(tert-butyl) 2-((5-(tert-butyl)diphenylsilyloxy)-3-methylpent-1-en-3-yl)diazenecarboxylate

Guidance literature:: With iodosylbenzene; In tetrahydrofuran; at 20 ℃; Inert atmosphere;
DOI:10.1021/ja2066219

Reference yield:

: 1332864-57-9
(E)-ethyl 5-((tert-butyl)diphenylsilyloxy)-3-methylpent-2-enoate

: 1332865-02-7
(E)-(tert-butyl) 2-((5-(tert-butyl)diphenylsilyloxy)-3-methylpent-1-en-3-yl)diazenecarboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: diisobutylaluminium hydride / tetrahydrofuran; hexane / -78 - 20 °C / Inert atmosphere

2: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

3: ethylenediamine / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

4: iodosylbenzene / tetrahydrofuran / 20 °C / Inert atmosphere

With di-isopropyl azodicarboxylate; iodosylbenzene; diisobutylaluminium hydride; ethylenediamine; triphenylphosphine; In tetrahydrofuran; hexane;
DOI:10.1021/ja2066219

Reference yield:

: 1332864-58-0
(E)-5-((tert-butyl)diphenylsilyloxy)-3-methylpent-2-en-1-ol

: 1332865-02-7
(E)-(tert-butyl) 2-((5-(tert-butyl)diphenylsilyloxy)-3-methylpent-1-en-3-yl)diazenecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

2: ethylenediamine / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

3: iodosylbenzene / tetrahydrofuran / 20 °C / Inert atmosphere

With di-isopropyl azodicarboxylate; iodosylbenzene; ethylenediamine; triphenylphosphine; In tetrahydrofuran;
DOI:10.1021/ja2066219