allyl (2-O-acetyl-3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->2)-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside

Base Information

• Chemical Name: allyl (2-O-acetyl-3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->2)-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside
• CAS No.: 672907-67-4
• Molecular Formula: C₉₂H₁₀₀O₂₀
• Molecular Weight: 1525.79
• Mol file: 672907-67-4.mol

Synonyms:allyl (2-O-acetyl-3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->2)-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside

Chemical Property of allyl (2-O-acetyl-3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->2)-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of allyl (2-O-acetyl-3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->2)-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside

There total 1 articles about allyl (2-O-acetyl-3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->2)-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

2-O-acetyl-3,4-di-O-benzyl-1-(2,2,2-trichloroethanimidate)-α/β-L-rhamnopyranoside (686767-31-7) + allyl (3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside (672907-44-7) → allyl (2-O-acetyl-3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->2)-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside (672907-67-4)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; In diethyl ether; at -30 - 20 ℃;

DOI:10.1021/jo035125b

Reference yield: 91.0%

allyl (2-O-acetyl-3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->2)-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside (672907-67-4) → benzoic acid 4-[3-(3-acetoxy-4,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-4,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy]-2-hydroxy-6-methyl-5-(3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl ester

Guidance literature:

allyl (2-O-acetyl-3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->2)-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside; (1,5-cyclooctadiene)[bis(methyldiphenylphosphine)]iridium(I) hexafluorophosphate; In tetrahydrofuran; at 20 ℃; for 2h;

With iodine; In tetrahydrofuran; water; at 20 ℃; for 1h;

DOI:10.1002/chem.200400903

Reference yield: 84.0%

allyl (2-O-acetyl-3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->2)-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside (672907-67-4) → allyl (3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->2)-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside

Guidance literature:

With tetrafluoroboric acid; In methanol; diethyl ether; at 20 ℃; for 120h;

DOI:10.1021/jo035125b

upstream raw materials:

2-O-acetyl-3,4-di-O-benzyl-1-(2,2,2-trichloroethanimidate)-α/β-L-rhamnopyranoside

allyl (3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside