(2R,3S)-methyl-1-(1-(2-bromophenyl)-2-nitroethyl)-2-oxocyclopentanecarboxylate

Base Information

Chemical Name:(2R,3S)-methyl-1-(1-(2-bromophenyl)-2-nitroethyl)-2-oxocyclopentanecarboxylate
CAS No.:1092784-93-4
Molecular Formula:C₁₅H₁₆BrNO₅
Molecular Weight:370.2
Hs Code.:

Synonyms:(2R,3S)-methyl-1-(1-(2-bromophenyl)-2-nitroethyl)-2-oxocyclopentanecarboxylate

Suppliers and Price of (2R,3S)-methyl-1-(1-(2-bromophenyl)-2-nitroethyl)-2-oxocyclopentanecarboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3S)-methyl-1-(1-(2-bromophenyl)-2-nitroethyl)-2-oxocyclopentanecarboxylate

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Technology Process of (2R,3S)-methyl-1-(1-(2-bromophenyl)-2-nitroethyl)-2-oxocyclopentanecarboxylate

There total 2 articles about (2R,3S)-methyl-1-(1-(2-bromophenyl)-2-nitroethyl)-2-oxocyclopentanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 65185-68-4
o-bromonitrostyrene

: 10472-24-9,265317-94-0
methyl 2-oxocyclopentane-1-carboxylate

: 1092784-93-4
(2R,3S)-methyl-1-(1-(2-bromophenyl)-2-nitroethyl)-2-oxocyclopentanecarboxylate

Guidance literature:: With 1-((1R,2R)-2-(dimethylamino)cyclohexyl)-3-((1R,2S)-2-hydroxy-1,2-diphenylethyl)thiourea; In dichloromethane; at -45 ℃; optical yield given as %ee; enantioselective reaction;
DOI:10.1002/chem.200801420

Reference yield: 93.0%

: 65185-68-4
(E)-2-bromo-β-nitrostyrene

: 10472-24-9,265317-94-0
methyl 2-oxocyclopentane-1-carboxylate

: 1092784-93-4
(2R,3S)-methyl-1-(1-(2-bromophenyl)-2-nitroethyl)-2-oxocyclopentanecarboxylate

Guidance literature:: With C₅₁H₄₂N₆; In toluene; at -10 ℃; for 45h; optical yield given as %ee; stereoselective reaction;
DOI:10.1016/j.tet.2011.05.005