7-Oxobicyclo[3.2.0]hept-2-ene-2-carboxylic acid

Base Information

Chemical Name:7-Oxobicyclo[3.2.0]hept-2-ene-2-carboxylic acid
CAS No.:78814-75-2
Molecular Formula:C₈H₈O₃
Molecular Weight:152.15
Hs Code.:
DSSTox Substance ID:DTXSID70541758
Mol file:78814-75-2.mol

Synonyms:78814-75-2;7-Oxobicyclo[3.2.0]hept-2-ene-2-carboxylic acid;SCHEMBL9664487;DTXSID70541758;VZCYBXLUHGMAJA-UHFFFAOYSA-N;7-oxobicyclo[3.2.0]hept-2-en-2-carboxylic acid

Suppliers and Price of 7-Oxobicyclo[3.2.0]hept-2-ene-2-carboxylic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 7-Oxobicyclo[3.2.0]hept-2-ene-2-carboxylic acid

Chemical Property:

PSA：54.37000
LogP:0.60630
XLogP3:0.1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:152.047344113
Heavy Atom Count:11
Complexity:265

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C=C(C2C1CC2=O)C(=O)O

Technology Process of 7-Oxobicyclo[3.2.0]hept-2-ene-2-carboxylic acid

There total 4 articles about 7-Oxobicyclo[3.2.0]hept-2-ene-2-carboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 78814-74-1
(1S,5S)-6,6-Dichloro-7-oxo-bicyclo[3.2.0]hept-2-ene-2-carboxylic acid

: 78814-75-2
4-carboxybicyclo<3.2.0>hepten-6-one

Guidance literature:: With acetic acid; zinc; at 70 ℃;
DOI:10.1016/S0040-4039(01)90464-2

Reference yield:

: 698-07-7
6,6-bis(methylthio)pentafulvene

: 78814-75-2
4-carboxybicyclo<3.2.0>hepten-6-one

Guidance literature:: Multi-step reaction with 4 steps

1: Et₂NH / diethyl ether / -10 °C

2: mercuric chloride, formic acid / Heating

3: 27 percent / 1:1 concentrated hydrochloric acid/glacial acetic acid

4: Zn, acetic acid / 70 °C

With hydrogenchloride; formic acid; acetic acid; diethylamine; mercury dichloride; zinc; In diethyl ether;
DOI:10.1016/S0040-4039(01)90464-2

Reference yield:

: 78814-66-1
(1S,5S)-6,6-Dichloro-7-oxo-bicyclo[3.2.0]hept-2-ene-2-carbothioic acid S-methyl ester

: 78814-75-2
4-carboxybicyclo<3.2.0>hepten-6-one

Guidance literature:: Multi-step reaction with 2 steps

1: 27 percent / 1:1 concentrated hydrochloric acid/glacial acetic acid

2: Zn, acetic acid / 70 °C

With hydrogenchloride; acetic acid; zinc;
DOI:10.1016/S0040-4039(01)90464-2