(C₆H₄)2SPt(P(C₆H₅)3)2Mn(CO)3⁽¹⁺⁾*BF₄^(1-)=(C₆H₄)2SPt(P(C₆H₅)3)2Mn(CO)3BF₄

Base Information

• Chemical Name: (C₆H₄)2SPt(P(C₆H₅)3)2Mn(CO)3⁽¹⁺⁾*BF₄^(1-)=(C₆H₄)2SPt(P(C₆H₅)3)2Mn(CO)3BF₄
• CAS No.: 211516-45-9
• Molecular Formula: BF₄*C₅₁H₃₈MnO₃P₂PtS
• Molecular Weight: 1129.7
• Mol file: 211516-45-9.mol

Synonyms:(C₆H₄)2SPt(P(C₆H₅)3)2Mn(CO)3⁽¹⁺⁾*BF₄^(1-)=(C₆H₄)2SPt(P(C₆H₅)3)2Mn(CO)3BF₄

Chemical Property of (C₆H₄)2SPt(P(C₆H₅)3)2Mn(CO)3⁽¹⁺⁾*BF₄^(1-)=(C₆H₄)2SPt(P(C₆H₅)3)2Mn(CO)3BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₆H₄)2SPt(P(C₆H₅)3)2Mn(CO)3⁽¹⁺⁾*BF₄^(1-)=(C₆H₄)2SPt(P(C₆H₅)3)2Mn(CO)3BF₄

There total 1 articles about (C₆H₄)2SPt(P(C₆H₅)3)2Mn(CO)3⁽¹⁺⁾*BF₄^(1-)=(C₆H₄)2SPt(P(C₆H₅)3)2Mn(CO)3BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

tris(triphenylphosphine)platinum(0) (13517-35-6) + [(η(6)-dibenzothiophene)Mn(CO)3]BF4 (158446-08-3) → (CO)3Mn(C12H8S)Pt(P(C6H5)3)2(1+)*BF4(1-)=[(CO)3Mn(C12H8S)Pt(P(C6H5)3)2]BF4 (211516-45-9)

Guidance literature:

In dichloromethane; N2-atmosphere; room temp. (15 min); evapn. (vac.), recrystn. (CH2Cl2 / Et2O); elem. anal.;

DOI:10.1021/om9802865

Reference yield: 50.0%

(C6H4)2SPt(P(C6H5)3)2Mn(CO)3(1+)*BF4(1-)=(C6H4)2SPt(P(C6H5)3)2Mn(CO)3BF4 (211516-45-9) → (C6H4)2SPt(P(C6H5)3)2Mn(CO)2(1+)*BF4(1-)=(C6H4)2SPt(P(C6H5)3)2Mn(CO)2BF4 (271601-21-9)

Guidance literature:

With (CH₃)3NO; In dichloromethane; byproducts: CO; 1 equiv. Me3NO was added to a soln. of Pt-complex under nitrogen at room temp., 10 min; soln. was concd., pptn. with Et2O, repptn. from diethyl ether, elem. anal.;

DOI:10.1021/om000100d

upstream raw materials:

tris(triphenylphosphine)platinum⁽⁰⁾

[(η(6)-dibenzothiophene)Mn(CO)3]BF4

Downstream raw materials:

(C₆H₄)2SPt(P(C₆H₅)3)2Mn(CO)2⁽¹⁺⁾*BF₄^(1-)=(C₆H₄)2SPt(P(C₆H₅)3)2Mn(CO)2BF₄