potassium (4-(1-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)vinyl)phenyl)trifluoroborate

Base Information

Chemical Name:potassium (4-(1-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)vinyl)phenyl)trifluoroborate
CAS No.:1572536-55-0
Molecular Formula:C₂₃H₂₇BF₃*K
Molecular Weight:410.372
Hs Code.:

Synonyms:potassium (4-(1-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)vinyl)phenyl)trifluoroborate

Suppliers and Price of potassium (4-(1-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)vinyl)phenyl)trifluoroborate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of potassium (4-(1-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)vinyl)phenyl)trifluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of potassium (4-(1-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)vinyl)phenyl)trifluoroborate

There total 2 articles about potassium (4-(1-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)vinyl)phenyl)trifluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 4,4,5,5-tetramethyl-2-(4-(1-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)vinyl)phenyl)-1,3,2-dioxaborolane

: 1572536-55-0
potassium (4-(1-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)vinyl)phenyl)trifluoroborate

Guidance literature:: With potassium hydrogen difluoride; In tetrahydrofuran; water; at 0 - 20 ℃; for 0.5h;
DOI:10.1021/ml500065q

Reference yield:

: 926038-65-5
2-(4-iodophenyl)-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-methanone

: 1572536-55-0
potassium (4-(1-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)vinyl)phenyl)trifluoroborate

Guidance literature:: Multi-step reaction with 3 steps

1.1: lithium hexamethyldisilazane / toluene / 0.25 h / -78 °C / Cooling with ice

1.2: -78 °C

2.1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 100 °C / Inert atmosphere

3.1: potassium hydrogen difluoride / tetrahydrofuran; water / 0.5 h / 0 - 20 °C

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium hydrogen difluoride; potassium acetate; lithium hexamethyldisilazane; In tetrahydrofuran; water; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ml500065q

Reference yield:

: 1572536-55-0
potassium (4-(1-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)vinyl)phenyl)trifluoroborate

: 10375-59-4
[11C]carbon dioxide

: 1572536-64-1
[¹¹C-carbonyl]4-[1-(3,5,5,8,8-pentamethyltetralin-2-yl)ethenyl]benzoic acid

Guidance literature:: With copper(I) thiophene-2-carboxylate; N,N,N,N,-tetramethylethylenediamine; tetrabutylammonium triphenyldifluorosilicate; In 1-methyl-pyrrolidin-2-one; at 100 ℃; for 0.0833333h; Reagent/catalyst; Solvent; Temperature; Inert atmosphere;
DOI:10.1021/ml500065q