(S)-2-[(S)-2-(4-Methoxy-benzyloxy)-pent-4-enyl]-1,4-dioxa-spiro[4.5]decane

Base Information

Chemical Name:(S)-2-[(S)-2-(4-Methoxy-benzyloxy)-pent-4-enyl]-1,4-dioxa-spiro[4.5]decane
CAS No.:866455-70-1
Molecular Formula:C₂₁H₃₀O₄
Molecular Weight:346.467
Hs Code.:

Synonyms:(S)-2-[(S)-2-(4-Methoxy-benzyloxy)-pent-4-enyl]-1,4-dioxa-spiro[4.5]decane

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Chemical Property of (S)-2-[(S)-2-(4-Methoxy-benzyloxy)-pent-4-enyl]-1,4-dioxa-spiro[4.5]decane

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Technology Process of (S)-2-[(S)-2-(4-Methoxy-benzyloxy)-pent-4-enyl]-1,4-dioxa-spiro[4.5]decane

There total 5 articles about (S)-2-[(S)-2-(4-Methoxy-benzyloxy)-pent-4-enyl]-1,4-dioxa-spiro[4.5]decane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 2746-25-0
p-Methoxybenzyl bromide

: 765300-71-8
(2S)-1[(2S)-1,4-dioxaspiro[4.5]decan-2-yl]pent-4-en-2-ol

: 866455-70-1
(S)-2-[(S)-2-(4-Methoxy-benzyloxy)-pent-4-enyl]-1,4-dioxa-spiro[4.5]decane

Guidance literature:: With sodium hydride; In tetrahydrofuran;
DOI:10.1016/j.tetlet.2005.07.075

Reference yield:

: 866455-67-6
(S)-1-(1,4-Dioxa-spiro[4.5]dec-2-yl)-pent-4-en-2-one

: 866455-70-1
(S)-2-[(S)-2-(4-Methoxy-benzyloxy)-pent-4-enyl]-1,4-dioxa-spiro[4.5]decane

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / LiAlH₄; LiI / diethyl ether; tetrahydrofuran / -100 °C

2: 87 percent / NaH / tetrahydrofuran

With lithium aluminium tetrahydride; sodium hydride; lithium iodide; In tetrahydrofuran; diethyl ether;
DOI:10.1016/j.tetlet.2005.07.075

Reference yield:

: 866455-65-4
1-[(2S)-1,4-dioxaspiro[4,5]dec-2-yl]-4-penten-2-ol

: 866455-70-1
(S)-2-[(S)-2-(4-Methoxy-benzyloxy)-pent-4-enyl]-1,4-dioxa-spiro[4.5]decane

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / IBX / dimethylsulfoxide; CH₂Cl₂ / 3 h

2: 94 percent / LiAlH₄; LiI / diethyl ether; tetrahydrofuran / -100 °C

3: 87 percent / NaH / tetrahydrofuran

With lithium aluminium tetrahydride; sodium hydride; lithium iodide; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; diethyl ether; dichloromethane; dimethyl sulfoxide;
DOI:10.1016/j.tetlet.2005.07.075