dodecyl 4,6-O-benzylidene-2,3-[15-cr-5]triazadiamido-β-D-glucopyranoside

Base Information

• Chemical Name: dodecyl 4,6-O-benzylidene-2,3-[15-cr-5]triazadiamido-β-D-glucopyranoside
• CAS No.: 1427214-30-9
• Molecular Formula: C₄₀H₅₉N₃O₈
• Molecular Weight: 709.924
• Mol file: 1427214-30-9.mol

Synonyms:dodecyl 4,6-O-benzylidene-2,3-[15-cr-5]triazadiamido-β-D-glucopyranoside

Chemical Property of dodecyl 4,6-O-benzylidene-2,3-[15-cr-5]triazadiamido-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dodecyl 4,6-O-benzylidene-2,3-[15-cr-5]triazadiamido-β-D-glucopyranoside

There total 9 articles about dodecyl 4,6-O-benzylidene-2,3-[15-cr-5]triazadiamido-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

dodecyl 4,6-O-benzylidene-2,3-bis-[2-(2-chloroacetamido)ethyl]-β-D-glucopyranoside (1427214-27-4) + benzylamine (100-46-9) → dodecyl 4,6-O-benzylidene-2,3-[15-cr-5]triazadiamido-β-D-glucopyranoside (1427214-30-9)

Guidance literature:

With sodium carbonate; In acetonitrile; for 12h; Reflux;

DOI:10.1016/j.tetlet.2013.01.025

Reference yield:

n-dodecyl-b-D-glucopyranoside (59122-55-3) → dodecyl 4,6-O-benzylidene-2,3-[15-cr-5]triazadiamido-β-D-glucopyranoside (1427214-30-9)

Guidance literature:

Multi-step reaction with 5 steps

1.1: toluene-4-sulfonic acid / dichloromethane

2.1: tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide / toluene; water / 0.5 h / 10 °C

2.2: 2 h

3.1: lithium aluminium tetrahydride / tetrahydrofuran / 1.5 h / 0 °C

4.1: dichloromethane / 0 - 20 °C

5.1: sodium carbonate / acetonitrile / 12 h / Reflux

With lithium aluminium tetrahydride; tetra(n-butyl)ammonium hydrogensulfate; sodium carbonate; toluene-4-sulfonic acid; sodium hydroxide; In tetrahydrofuran; dichloromethane; water; toluene; acetonitrile;

DOI:10.1016/j.tetlet.2013.01.025

Reference yield:

dodecyl 4,6-O-benzylidene-2,3-bis-(2-aminoethyl)-β-D-glucopyranoside (1427214-25-2) → dodecyl 4,6-O-benzylidene-2,3-[15-cr-5]triazadiamido-β-D-glucopyranoside (1427214-30-9)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane / 0 - 20 °C

2: sodium carbonate / acetonitrile / 12 h / Reflux

With sodium carbonate; In dichloromethane; acetonitrile;

DOI:10.1016/j.tetlet.2013.01.025

upstream raw materials:

dodecyl 4,6-O-benzylidene-2,3-bis-[2-(2-chloroacetamido)ethyl]-β-D-glucopyranoside

benzylamine

β-D-glucose pentaacetate

1-n-dodecyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside