tert-butyl(trichloromethyl)phosphinous chloride

Base Information

• Chemical Name: tert-butyl(trichloromethyl)phosphinous chloride
• CAS No.: 117965-89-6
• Molecular Formula: C₅H₉Cl₄P
• Molecular Weight: 241.912
• Mol file: 117965-89-6.mol

Synonyms:tert-butyl(trichloromethyl)phosphinous chloride

Chemical Property of tert-butyl(trichloromethyl)phosphinous chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-butyl(trichloromethyl)phosphinous chloride

There total 1 articles about tert-butyl(trichloromethyl)phosphinous chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

tert-butylpivaloylphosphine (67033-63-0) → tert-butyl(trichloromethyl)phosphinous chloride (117965-89-6) + tert-butylpivaloylphosphinic acid chloride (131551-82-1) + tert-butyldichlorophosphine (25979-07-1)

Guidance literature:

With tetrachloromethane; triethylamine; palladium dichloride; at 100 ℃; for 2h; Product distribution; also with Cu powder;

Reference yield: 57.0%

tert-butyl(trichloromethyl)phosphinous chloride (117965-89-6) + aniline (62-53-3) → P-(tert-butyl)-N-phenyl-P-(trichloromethyl)phosphinoselenoic amide (1232774-61-6)

Guidance literature:

With pyridine; selenium; sodium iodide; at 5 - 15 ℃; for 48.5h; Inert atmosphere;

DOI:10.1016/j.tet.2010.03.087

upstream raw materials:

tert-butylpivaloylphosphine

Downstream raw materials:

P-(tert-butyl)-N-phenyl-P-(trichloromethyl)phosphinoselenoic amide