2-(3,5-dimethylphenyl)-6,7-dihydro-3H-[1,4]diazepino[1,2,3,4-lmn][1,10]phenanthroline-3,9(5H)-dione

Base Information

Chemical Name:2-(3,5-dimethylphenyl)-6,7-dihydro-3H-[1,4]diazepino[1,2,3,4-lmn][1,10]phenanthroline-3,9(5H)-dione
CAS No.:1422669-72-4
Molecular Formula:C₂₃H₂₀N₂O₂
Molecular Weight:356.424
Hs Code.:

Synonyms:2-(3,5-dimethylphenyl)-6,7-dihydro-3H-[1,4]diazepino[1,2,3,4-lmn][1,10]phenanthroline-3,9(5H)-dione

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Chemical Property of 2-(3,5-dimethylphenyl)-6,7-dihydro-3H-[1,4]diazepino[1,2,3,4-lmn][1,10]phenanthroline-3,9(5H)-dione

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Technology Process of 2-(3,5-dimethylphenyl)-6,7-dihydro-3H-[1,4]diazepino[1,2,3,4-lmn][1,10]phenanthroline-3,9(5H)-dione

There total 3 articles about 2-(3,5-dimethylphenyl)-6,7-dihydro-3H-[1,4]diazepino[1,2,3,4-lmn][1,10]phenanthroline-3,9(5H)-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

: 108-38-3,104809-90-7
m-xylene

: 39588-59-5
3,6,7,9-tetrahydro-5H-<1,4>diazepino<1,2,3,4-lmn><1,10>phenanthroline-3,9-dione

: 1422669-72-4
2-(3,5-dimethylphenyl)-6,7-dihydro-3H-[1,4]diazepino[1,2,3,4-lmn][1,10]phenanthroline-3,9(5H)-dione

: 1422669-73-5
2,10-bis(3,5-dimethylphenyl)-6,7-dihydro-3H-[1,4]diazepino[1,2,3,4-lmn][1,10]phenanthroline-3,9(5H)-dione

Guidance literature:: With palladium(II) trifluoroacetate; silver carbonate; Trimethylacetic acid; at 20 - 130 ℃; for 48h; Inert atmosphere; Schlenk technique;
DOI:10.1039/c2ob27325j

Reference yield:

: 66-71-7
1,10-Phenanthroline

: 1422669-72-4
2-(3,5-dimethylphenyl)-6,7-dihydro-3H-[1,4]diazepino[1,2,3,4-lmn][1,10]phenanthroline-3,9(5H)-dione

: 1422669-73-5
2,10-bis(3,5-dimethylphenyl)-6,7-dihydro-3H-[1,4]diazepino[1,2,3,4-lmn][1,10]phenanthroline-3,9(5H)-dione

Guidance literature:: Multi-step reaction with 3 steps

1.1: nitrobenzene / 4 h / 120 °C / Inert atmosphere

2.1: potassium hexacyanoferrate(III); sodium hydroxide; water / 2 h / 0 - 5 °C / pH 7 - 8 / Inert atmosphere

2.2: pH 7 - 8 / Inert atmosphere

3.1: palladium(II) trifluoroacetate; silver carbonate; Trimethylacetic acid / 48 h / 20 - 130 °C / Inert atmosphere; Schlenk technique

With palladium(II) trifluoroacetate; water; silver carbonate; sodium hydroxide; potassium hexacyanoferrate(III); Trimethylacetic acid; In nitrobenzene;
DOI:10.1039/c2ob27325j

Reference yield:

: 15302-99-5
6,7-dihydro-5H-[1,4]diazepino[1,2,3,4-l,m,n][1,10]phenanthroline-4,8-diium dibromide

: 1422669-72-4
2-(3,5-dimethylphenyl)-6,7-dihydro-3H-[1,4]diazepino[1,2,3,4-lmn][1,10]phenanthroline-3,9(5H)-dione

: 1422669-73-5
2,10-bis(3,5-dimethylphenyl)-6,7-dihydro-3H-[1,4]diazepino[1,2,3,4-lmn][1,10]phenanthroline-3,9(5H)-dione

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium hexacyanoferrate(III); sodium hydroxide; water / 2 h / 0 - 5 °C / pH 7 - 8 / Inert atmosphere

1.2: pH 7 - 8 / Inert atmosphere

2.1: palladium(II) trifluoroacetate; silver carbonate; Trimethylacetic acid / 48 h / 20 - 130 °C / Inert atmosphere; Schlenk technique

With palladium(II) trifluoroacetate; water; silver carbonate; sodium hydroxide; potassium hexacyanoferrate(III); Trimethylacetic acid;
DOI:10.1039/c2ob27325j