[3,4-13C2]-(6α,7α,12α)-12-(benzoyloxy)-6,7-epoxy-3-oxochol-4-en-24-oic acid methyl ester

Base Information

Chemical Name:[3,4-13C2]-(6α,7α,12α)-12-(benzoyloxy)-6,7-epoxy-3-oxochol-4-en-24-oic acid methyl ester
CAS No.:473462-23-6
Molecular Formula:C₃₂H₄₀O₆
Molecular Weight:522.644
Hs Code.:

Synonyms:[3,4-13C2]-(6α,7α,12α)-12-(benzoyloxy)-6,7-epoxy-3-oxochol-4-en-24-oic acid methyl ester

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Chemical Property of [3,4-13C2]-(6α,7α,12α)-12-(benzoyloxy)-6,7-epoxy-3-oxochol-4-en-24-oic acid methyl ester

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Technology Process of [3,4-13C2]-(6α,7α,12α)-12-(benzoyloxy)-6,7-epoxy-3-oxochol-4-en-24-oic acid methyl ester

There total 1 articles about [3,4-13C2]-(6α,7α,12α)-12-(benzoyloxy)-6,7-epoxy-3-oxochol-4-en-24-oic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 473462-21-4
[3,4-13C2]-(12α)-12-(benzoyloxy)-3-oxochola-4,6-dien-24-oic acid methyl ester

: 473462-23-6
[3,4-13C2]-(6α,7α,12α)-12-(benzoyloxy)-6,7-epoxy-3-oxochol-4-en-24-oic acid methyl ester

Guidance literature:: With 70percent m-chloroperbenzoic acid; In dichloromethane; at 4 ℃; for 48h;
DOI:10.1021/jo0259109

Reference yield:

: 473462-23-6
[3,4-13C2]-(6α,7α,12α)-12-(benzoyloxy)-6,7-epoxy-3-oxochol-4-en-24-oic acid methyl ester

: 473462-24-7
[3,4-13C2]-(5β,7α,12α)-12-(benzoyloxy)-7-hydroxy-3-oxocholan-24-oic acid methyl ester

Guidance literature:: With pyridine; hydrogen; 10percent Pd/C; for 18h; under 3102.97 Torr;
DOI:10.1021/jo0259109

Reference yield:

: 473462-23-6
[3,4-13C2]-(6α,7α,12α)-12-(benzoyloxy)-6,7-epoxy-3-oxochol-4-en-24-oic acid methyl ester

: C₃₀⁽¹³⁾C₂H₄₆O₆

Guidance literature:: Multi-step reaction with 2 steps

1: hydrogen; pyridine / 10percent Pd/C / 18 h / 3102.97 Torr

2: lithium tri-tert-butoxyaluminohydride / tetrahydrofuran / -78 °C

With pyridine; lithium tri(t-butoxy)aluminum hydride; hydrogen; 10percent Pd/C; In tetrahydrofuran;
DOI:10.1021/jo0259109