1,2,3,4-di-O-isopropylidene-D-galactopyranosyl anthraquinon-2-ylmethoxycarbonate

Base Information

• Chemical Name: 1,2,3,4-di-O-isopropylidene-D-galactopyranosyl anthraquinon-2-ylmethoxycarbonate
• CAS No.: 350498-57-6
• Molecular Formula: C₂₈H₂₈O₁₀
• Molecular Weight: 524.524
• Mol file: 350498-57-6.mol

Synonyms:1,2,3,4-di-O-isopropylidene-D-galactopyranosyl anthraquinon-2-ylmethoxycarbonate

Chemical Property of 1,2,3,4-di-O-isopropylidene-D-galactopyranosyl anthraquinon-2-ylmethoxycarbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,2,3,4-di-O-isopropylidene-D-galactopyranosyl anthraquinon-2-ylmethoxycarbonate

There total 1 articles about 1,2,3,4-di-O-isopropylidene-D-galactopyranosyl anthraquinon-2-ylmethoxycarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-methylanthracene-9,10-dione (84-54-8) → 1,2,3,4-di-O-isopropylidene-D-galactopyranosyl anthraquinon-2-ylmethoxycarbonate (350498-57-6)

Guidance literature:

Multi-step reaction with 4 steps

1: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / benzene

2: calcium carbonate / water; 1,4-dioxane

3: dmap / dichloromethane

4: dmap / dichloromethane

With dmap; N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); calcium carbonate; In 1,4-dioxane; dichloromethane; water; benzene;

DOI:10.1021/acs.joc.8b02252

Reference yield: 66.0%

1,2,3,4-di-O-isopropylidene-D-galactopyranosyl anthraquinon-2-ylmethoxycarbonate (350498-57-6) → bis(1,2,3,4-di-O-isopropylidene-D-galactopyranosyl)carbonate (18485-12-6) + 1,2:3,4-di-O-isopropylidene-α-D-galactopyranose (4064-06-6)

Guidance literature:

In tetrahydrofuran; water; Photolysis;

DOI:10.1021/ol015787s

Reference yield:

1,2,3,4-di-O-isopropylidene-D-galactopyranosyl anthraquinon-2-ylmethoxycarbonate (350498-57-6) → 1,2:3,4-di-O-isopropylidene-α-D-galactopyranose (4064-06-6)

Guidance literature:

In tetrahydrofuran; water; Quantum yield; Kinetics; Photolysis;

DOI:10.1021/ol015787s

upstream raw materials:

2-methylanthracene-9,10-dione

Downstream raw materials:

1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

bis(1,2,3,4-di-O-isopropylidene-D-galactopyranosyl)carbonate