[Cu(bis[2-(diphenylphosphino)phenyl]-ether)2(2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole)]BF₄

Base Information

• Chemical Name: [Cu(bis[2-(diphenylphosphino)phenyl]-ether)2(2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole)]BF₄
• CAS No.: 1245722-55-7
• Molecular Formula: BF₄*C₅₀H₃₉CuN₃O₂P₂
• Molecular Weight: 926.177
• Mol file: 1245722-55-7.mol

Synonyms:[Cu(bis[2-(diphenylphosphino)phenyl]-ether)2(2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole)]BF₄

Chemical Property of [Cu(bis[2-(diphenylphosphino)phenyl]-ether)2(2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole)]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Cu(bis[2-(diphenylphosphino)phenyl]-ether)2(2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole)]BF₄

There total 5 articles about [Cu(bis[2-(diphenylphosphino)phenyl]-ether)2(2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole)]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

tetrakis(acetonitrile)copper(I)tetrafluoroborate + 2-(pyridyl-2-yl)-5-(p-tolyl)-1,3,4-oxadiazole (1171635-04-3) + bis[2-(diphenylphosphino)phenyl] ether (166330-10-5) → [Cu(bis[2-(diphenylphosphino)phenyl]-ether)2(2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole)]BF4 (1245722-55-7)

Guidance literature:

In dichloromethane; Cu compd. and P compd. refluxed in CH2Cl2 for 30 min, ligand added (1:1:1 molar ratio), refluxed for 30 min; evapd., recrystd. (THF/ether), elem. anal.;

DOI:10.1016/j.ica.2010.04.041

Reference yield: 76.0%

tetrakis(acetonitrile)copper(I)tetrafluoroborate + 2-(pyridyl-2-yl)-5-(p-tolyl)-1,3,4-oxadiazole (1171635-04-3) + 4,4'-bis(diphenylphosphoryl)diphenylether (10211-98-0) → [Cu(bis[2-(diphenylphosphino)phenyl]-ether)2(2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole)]BF4 (1245722-55-7)

Guidance literature:

In dichloromethane; for 1h;

DOI:10.1016/j.ica.2013.02.020

Reference yield:

2-Cyanopyridine (100-70-9,1232006-36-8) → [Cu(bis[2-(diphenylphosphino)phenyl]-ether)2(2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole)]BF4 (1245722-55-7)

Guidance literature:

Multi-step reaction with 3 steps

1: sodium azide; zinc dibromide / water / 6 h / Reflux

2: pyridine / Reflux

3: dichloromethane / 1 h

With sodium azide; zinc dibromide; In pyridine; dichloromethane; water;

DOI:10.1016/j.ica.2013.02.020

upstream raw materials:

2-(pyridyl-2-yl)-5-(p-tolyl)-1,3,4-oxadiazole

bis[2-(diphenylphosphino)phenyl] ether

4,4'-bis(diphenylphosphoryl)diphenylether

2-Cyanopyridine