C₃₅H₅₄O₇Si

Base Information

Chemical Name:C₃₅H₅₄O₇Si
CAS No.:1209386-14-0
Molecular Formula:C₃₅H₅₄O₇Si
Molecular Weight:614.895
Hs Code.:

C<sub>35</sub>H<sub>54</sub>O<sub>7</sub>Si

Synonyms:C₃₅H₅₄O₇Si

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Chemical Property of C₃₅H₅₄O₇Si

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Technology Process of C₃₅H₅₄O₇Si

There total 12 articles about C₃₅H₅₄O₇Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₉H₂₈O₄

: 1209386-14-0
C₃₅H₅₄O₇Si

Guidance literature:: Multi-step reaction with 11 steps

1: trifluorormethanesulfonic acid / dichloromethane; cyclohexane / 0.5 h / 20 °C / Inert atmosphere

2: diisobutylaluminium hydride / dichloromethane; hexane / 0.08 h / -78 °C / Inert atmosphere

3: L-(+)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / -20 °C / Inert atmosphere; Molecular sieve

4: dimethyl sulfoxide; sulfur trioxide pyridine complex; triethylamine / dichloromethane / 1.5 h / 0 °C / Inert atmosphere

5: dichloromethane / 0.02 h / 0 °C / Inert atmosphere

6: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; tributylphosphine; formic acid; triethylamine / 1,4-dioxane / 9.5 h / 20 °C / Inert atmosphere

7: 2,6-dimethylpyridine / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

8: diisobutylaluminium hydride / dichloromethane; hexane / 0.12 h / -78 °C / Inert atmosphere

9: D-(-)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / 4 h / -20 °C / Inert atmosphere; Molecular sieve

10: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hypochlorite; sodium chlorite / acetonitrile / 1.5 h / pH 7 / Inert atmosphere

11: diethyl ether / 0 °C / Inert atmosphere

With 2,6-dimethylpyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium hypochlorite; sodium chlorite; formic acid; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; L-(+)-diisopropyl tartrate; tributylphosphine; trifluorormethanesulfonic acid; sulfur trioxide pyridine complex; diisobutylaluminium hydride; D-(-)-diisopropyl tartrate; dimethyl sulfoxide; triethylamine; In 1,4-dioxane; diethyl ether; decane; hexane; dichloromethane; cyclohexane; acetonitrile; 3: |Sharpless Asymmetric Epoxidation / 4: |Parikh-Doering Oxidation / 5: |Horner-Wadsworth-Emmons Olefination / 9: |Sharpless Asymmetric Epoxidation;
DOI:10.1021/jo400260m

Reference yield:

: C₂₇H₃₆O₅

: 1209386-14-0
C₃₅H₅₄O₇Si

Guidance literature:: Multi-step reaction with 10 steps

1: diisobutylaluminium hydride / dichloromethane; hexane / 0.08 h / -78 °C / Inert atmosphere

2: L-(+)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / -20 °C / Inert atmosphere; Molecular sieve

3: dimethyl sulfoxide; sulfur trioxide pyridine complex; triethylamine / dichloromethane / 1.5 h / 0 °C / Inert atmosphere

4: dichloromethane / 0.02 h / 0 °C / Inert atmosphere

5: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; tributylphosphine; formic acid; triethylamine / 1,4-dioxane / 9.5 h / 20 °C / Inert atmosphere

6: 2,6-dimethylpyridine / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

7: diisobutylaluminium hydride / dichloromethane; hexane / 0.12 h / -78 °C / Inert atmosphere

8: D-(-)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / 4 h / -20 °C / Inert atmosphere; Molecular sieve

9: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hypochlorite; sodium chlorite / acetonitrile / 1.5 h / pH 7 / Inert atmosphere

10: diethyl ether / 0 °C / Inert atmosphere

With 2,6-dimethylpyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium hypochlorite; sodium chlorite; formic acid; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; L-(+)-diisopropyl tartrate; tributylphosphine; sulfur trioxide pyridine complex; diisobutylaluminium hydride; D-(-)-diisopropyl tartrate; dimethyl sulfoxide; triethylamine; In 1,4-dioxane; diethyl ether; decane; hexane; dichloromethane; acetonitrile; 2: |Sharpless Asymmetric Epoxidation / 3: |Parikh-Doering Oxidation / 4: |Horner-Wadsworth-Emmons Olefination / 8: |Sharpless Asymmetric Epoxidation;
DOI:10.1021/jo400260m

Reference yield:

: C₁₈H₂₄O₄

: 1209386-14-0
C₃₅H₅₄O₇Si

Guidance literature:: Multi-step reaction with 12 steps

1: water; trimethylaluminum / dichloromethane; hexane / -40 - 0 °C / Inert atmosphere

2: trifluorormethanesulfonic acid / dichloromethane; cyclohexane / 0.5 h / 20 °C / Inert atmosphere

3: diisobutylaluminium hydride / dichloromethane; hexane / 0.08 h / -78 °C / Inert atmosphere

4: L-(+)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / -20 °C / Inert atmosphere; Molecular sieve

5: dimethyl sulfoxide; sulfur trioxide pyridine complex; triethylamine / dichloromethane / 1.5 h / 0 °C / Inert atmosphere

6: dichloromethane / 0.02 h / 0 °C / Inert atmosphere

7: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; tributylphosphine; formic acid; triethylamine / 1,4-dioxane / 9.5 h / 20 °C / Inert atmosphere

8: 2,6-dimethylpyridine / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

9: diisobutylaluminium hydride / dichloromethane; hexane / 0.12 h / -78 °C / Inert atmosphere

10: D-(-)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / 4 h / -20 °C / Inert atmosphere; Molecular sieve

11: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hypochlorite; sodium chlorite / acetonitrile / 1.5 h / pH 7 / Inert atmosphere

12: diethyl ether / 0 °C / Inert atmosphere

With 2,6-dimethylpyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium hypochlorite; sodium chlorite; formic acid; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; L-(+)-diisopropyl tartrate; tributylphosphine; trifluorormethanesulfonic acid; water; trimethylaluminum; sulfur trioxide pyridine complex; diisobutylaluminium hydride; D-(-)-diisopropyl tartrate; dimethyl sulfoxide; triethylamine; In 1,4-dioxane; diethyl ether; decane; hexane; dichloromethane; cyclohexane; acetonitrile; 4: |Sharpless Asymmetric Epoxidation / 5: |Parikh-Doering Oxidation / 6: |Horner-Wadsworth-Emmons Olefination / 10: |Sharpless Asymmetric Epoxidation;
DOI:10.1021/jo400260m