((CH₃)(C₆H₅)2P)2PdC(CN)2C(CF₃)2

Base Information

• Chemical Name: ((CH₃)(C₆H₅)2P)2PdC(CN)2C(CF₃)2
• CAS No.: 36562-07-9
• Molecular Formula: C₃₂H₂₆F₆N₂P₂Pd
• Molecular Weight: 720.93
• Mol file: 36562-07-9.mol

Synonyms:((CH₃)(C₆H₅)2P)2PdC(CN)2C(CF₃)2

Chemical Property of ((CH₃)(C₆H₅)2P)2PdC(CN)2C(CF₃)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((CH₃)(C₆H₅)2P)2PdC(CN)2C(CF₃)2

There total 1 articles about ((CH₃)(C₆H₅)2P)2PdC(CN)2C(CF₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

tetrakis(methyldiphenylphosphine)palladium (24981-80-4) + 1,1-dicyano-2,2-bis(trifluoromethyl)ethene (1113-69-5) → ((CH3)(C6H5)2P)2PdC(CN)2C(CF3)2 (36562-07-9)

Guidance literature:

In benzene; (N2); dropwise addn. of 1,1-dicyano-2,2-bis(trifluoromethyl)ethylene soln. to soln. of the Pd-complex; stirring at room temp. for 1 h; removal of solvent under reduced pressure; triturating the residue withn-hexane; crystn. from. methylene chloride-diethyl ether; elem. anal.;

DOI:10.1016/0022-1902(81)80620-3

Reference yield: 95.0%

((CH3)(C6H5)2P)2PdC(CN)2C(CF3)2 (36562-07-9) → ((CH3)(C6H5)2P)2Pd(CN)(C(CN)C(CF3)2)

Guidance literature:

With silver(I) acetate; In acetone; (N2); adding an excess silver acetate to a stirred soln. of the Pd-complex; 72 h; filtration; removal of solvent under reduced pressure; dissolving the residue in a small vol. of methylene chloride; filtration through Florisil; elem. anal.;

DOI:10.1016/0022-1902(81)80620-3

upstream raw materials:

tetrakis(methyldiphenylphosphine)palladium

1,1-dicyano-2,2-bis(trifluoromethyl)ethene