(N,N'-diisopropylaminotroponiminate)Al(CH₂Ph)2

Base Information

• Chemical Name: (N,N'-diisopropylaminotroponiminate)Al(CH₂Ph)2
• CAS No.: 365215-43-6
• Molecular Formula: C₂₇H₃₃AlN₂
• Molecular Weight: 412.554
• Mol file: 365215-43-6.mol

Synonyms:(N,N'-diisopropylaminotroponiminate)Al(CH₂Ph)2

Chemical Property of (N,N'-diisopropylaminotroponiminate)Al(CH₂Ph)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (N,N'-diisopropylaminotroponiminate)Al(CH₂Ph)2

There total 2 articles about (N,N'-diisopropylaminotroponiminate)Al(CH₂Ph)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

(N,N'-diisopropylaminotroponiminate)AlCl2 (365215-41-4) + Mg(CH2Ph)2(THF)2 → (N,N'-diisopropylaminotroponiminate)Al(CH2Ph)2 (365215-43-6)

Guidance literature:

In hexane; under N2 atm. to soln. (iPr2-ATI)AlCl2 in hexane was added Mg(CH2Ph)2*2THF and stirred for 16 h at room temp.; soln. was filtered, solvent was evapd. under vac., residue was dissolvedin pentane, dioxane was added, soln. was cooled to -37°C for 16 h, ppt. was filtered off, filtrate was evapd. under vac.;

DOI:10.1021/ja010242e

Reference yield:

lithium N,N-diisopropylaminotroponiminate → (N,N'-diisopropylaminotroponiminate)Al(CH2Ph)2 (365215-43-6)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: hexane

In hexane; toluene;

DOI:10.1021/ja010242e

Reference yield:

(N,N'-diisopropylaminotroponiminate)Al(CH2Ph)2 (365215-43-6) + trityl tetrakis(pentafluorophenyl)borate → (pentafluorophenyl)2B(benzyl) (199607-95-9) + B(benzyl)2(pentafluorophenyl) (199607-96-0) + (N,N'-diisopropylaminotroponiminate)Al(CH2Ph)(C6F5) (365215-51-6) + tribenzylborane (1694-84-4)

Guidance literature:

In hexane; byproducts: Ph3CCH2Ph; under N2 atm. to soln. (iPr2-ATI)Al(CH2Ph)2 in hexane was added (Ph3C)(B(C6F5)4) and stirred at room temp. for 48 h; ppt. was filtered off, filtrate was evapd.;

DOI:10.1021/ja010242e

upstream raw materials:

(N,N'-diisopropylaminotroponiminate)AlCl₂

Downstream raw materials:

(pentafluorophenyl)2B(benzyl)

B(benzyl)2(pentafluorophenyl)

(N,N'-diisopropylaminotroponiminate)Al(CH₂Ph)(C₆F₅)

tribenzylborane