[Ru(2,2'-bipyridine)2(3'-(diphenylphosphino)-2,2':5',2''-terthiophene-P,C)](PF₆)

Base Information

• Chemical Name: [Ru(2,2'-bipyridine)2(3'-(diphenylphosphino)-2,2':5',2''-terthiophene-P,C)](PF₆)
• CAS No.: 507224-10-4
• Molecular Formula: C₄₄H₃₂N₄PRuS₃*F₆P
• Molecular Weight: 989.971
• Mol file: 507224-10-4.mol

Synonyms:[Ru(2,2'-bipyridine)2(3'-(diphenylphosphino)-2,2':5',2''-terthiophene-P,C)](PF₆)

Chemical Property of [Ru(2,2'-bipyridine)2(3'-(diphenylphosphino)-2,2':5',2''-terthiophene-P,C)](PF₆)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(2,2'-bipyridine)2(3'-(diphenylphosphino)-2,2':5',2''-terthiophene-P,C)](PF₆)

There total 1 articles about [Ru(2,2'-bipyridine)2(3'-(diphenylphosphino)-2,2':5',2''-terthiophene-P,C)](PF₆) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

ammonium hexafluorophosphate + [Ru(2,2'-bipyridine)2(3'-(diphenylphosphino)-2,2':5',2''-terthiophene-P,S)](PF6)2 → [Ru(2,2'-bipyridine)2(3'-(diphenylphosphino)-2,2':5',2''-terthiophene-P,C)](PF6) (507224-10-4)

Guidance literature:

With sodium hydroxide; In methanol; water; NaOH (18 mmol) added to Ru compd. (0.521 mmol) in methanol, refluxed for18 h, concd., aq. soln. of NH4PF6 (10.4 mmol) added, pptd.; filtered, washed (water, ether), recrystd. (ethanol/acetone=9:1);

DOI:10.1021/ja043573a

Reference yield: 99.0%

[Ru(2,2'-bipyridine)2(3'-(diphenylphosphino)-2,2':5',2''-terthiophene-P,C)](PF6) (507224-10-4) → [Ru(2,2'-bipyridine)2(3'-(diphenylphosphino)-2,2':5',2''-terthiophene-P,S)](PF6)2

Guidance literature:

With hydrogenchloride; In neat (no solvent); at room temp.; NMR;

DOI:10.1021/ja043573a

Reference yield: 99.0%

hexafluorophosphoric acid + [Ru(2,2'-bipyridine)2(3'-(diphenylphosphino)-2,2':5',2''-terthiophene-P,C)](PF6) (507224-10-4) → [Ru(2,2'-bipyridine)2(3'-(diphenylphosphino)-2,2':5',2''-terthiophene-P,S)](PF6)2

Guidance literature:

In neat (no solvent); at room temp.; NMR;

DOI:10.1021/ja043573a