4'-(2-(4-(2,2'-bipyridin-5-ylcarbonylamino)butoxy)-3-carboxylphenyl)-2,2';6',2''-terpyridine

Base Information

• Chemical Name: 4'-(2-(4-(2,2'-bipyridin-5-ylcarbonylamino)butoxy)-3-carboxylphenyl)-2,2';6',2''-terpyridine
• CAS No.: 1374393-26-6
• Molecular Formula: C₃₇H₃₀N₆O₄
• Molecular Weight: 622.683
• Mol file: 1374393-26-6.mol

Synonyms:4'-(2-(4-(2,2'-bipyridin-5-ylcarbonylamino)butoxy)-3-carboxylphenyl)-2,2';6',2''-terpyridine

Chemical Property of 4'-(2-(4-(2,2'-bipyridin-5-ylcarbonylamino)butoxy)-3-carboxylphenyl)-2,2';6',2''-terpyridine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4'-(2-(4-(2,2'-bipyridin-5-ylcarbonylamino)butoxy)-3-carboxylphenyl)-2,2';6',2''-terpyridine

There total 1 articles about 4'-(2-(4-(2,2'-bipyridin-5-ylcarbonylamino)butoxy)-3-carboxylphenyl)-2,2';6',2''-terpyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

4'-(2-(4-(2,2'-bipyridin-5-ylcarbonylamino)butoxy)-3-methoxycarbonylphenyl)-2,2';6',2''-terpyridine (1186611-96-0) → 4'-(2-(4-(2,2'-bipyridin-5-ylcarbonylamino)butoxy)-3-carboxylphenyl)-2,2';6',2''-terpyridine (1374393-26-6)

Guidance literature:

With water; sodium hydroxide; In tetrahydrofuran; methanol; at 50 ℃; for 12h;

DOI:10.1002/chem.201100502

Reference yield:

C19H31N3O4 (1374393-25-5) + 4'-(2-(4-(2,2'-bipyridin-5-ylcarbonylamino)butoxy)-3-carboxylphenyl)-2,2';6',2''-terpyridine (1374393-26-6) → C56H59N9O7 (1374393-27-7)

Guidance literature:

With dmap; 1-hydroxybenzotriazol-hydrate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; at 20 ℃; for 12h;

DOI:10.1002/chem.201100502

Reference yield:

C19H31N3O4 (1374393-25-5) + 4'-(2-(4-(2,2'-bipyridin-5-ylcarbonylamino)butoxy)-3-carboxylphenyl)-2,2';6',2''-terpyridine (1374393-26-6) → C51H51N9O5 (1374393-28-8)

Guidance literature:

Multi-step reaction with 2 steps

1: dmap; 1-hydroxybenzotriazol-hydrate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 12 h / 20 °C

2: trifluoroacetic acid / 2 h / 20 °C

With dmap; 1-hydroxybenzotriazol-hydrate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; trifluoroacetic acid; In dichloromethane;

DOI:10.1002/chem.201100502

upstream raw materials:

4'-(2-(4-(2,2'-bipyridin-5-ylcarbonylamino)butoxy)-3-methoxycarbonylphenyl)-2,2';6',2''-terpyridine

Downstream raw materials:

C₅₆H₅₉N₉O₇

C₅₁H₅₁N₉O₅