phenylphosphine pentacarbonylmolybdenum⁽⁰⁾

Base Information

• Chemical Name: phenylphosphine pentacarbonylmolybdenum⁽⁰⁾
• CAS No.: 72868-86-1
• Molecular Formula: C₁₁H₇MoO₅P
• Molecular Weight: 346.087
• Mol file: 72868-86-1.mol

Synonyms:phenylphosphine pentacarbonylmolybdenum⁽⁰⁾

Chemical Property of phenylphosphine pentacarbonylmolybdenum⁽⁰⁾

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of phenylphosphine pentacarbonylmolybdenum⁽⁰⁾

There total 6 articles about phenylphosphine pentacarbonylmolybdenum⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

phenylphosphane (638-21-1) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → phenylphosphine pentacarbonylmolybdenum(0) (72868-86-1)

Guidance literature:

With methanol; In Petroleum ether; byproducts: CO; mixt. warmed at 110°C for 6 h under stirring, solvents removed in vac. (0.1 Torr/20-40°C), residue decompd. with MeOH, stirred for 30 min, Mo(CO)6 filtered, MeOH removed in vac.; residue sublimed (1E-4 Torr/55-60°C);

Reference yield: 40.0%

bis(piperidyl)tetracarbonylmolybdenum(0) (65337-26-0,59967-36-1) + phenylphosphane (638-21-1) → phenylphosphine pentacarbonylmolybdenum(0) (72868-86-1) + (CO)4Mo((C6H5)PH2)2 (73985-32-7)

Guidance literature:

In dichloromethane; (N2); reflux (15 min), solvent evapn.; chromy., recrystn. (-20°C, overnight); elem. anal.;

DOI:10.1016/0277-5387(95)00321-5

Reference yield:

Dichlorophenylphosphine (644-97-3) → phenylphosphine pentacarbonylmolybdenum(0) (72868-86-1)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: diethyl ether

In tetrahydrofuran; diethyl ether;

upstream raw materials:

lithium aluminium tetrahydride

((C₆H₅)PCl₂)Mo(CO)5

phenylphosphane

molybdenum hexacarbonyl

Downstream raw materials:

Co₄(CO)₁₀(μ₄-PPh)₂

molybdenum hexacarbonyl

((C₆H₅)PH(P(O)(OC₂H₅)2))Mo(CO)5

pentacarbonyl(1,1,2,3,3-pentaphenyltriphosphine-P⁽²⁾)molydenum⁽⁰⁾