C₆₇H₈₃N₃O₄S₄Si

Base Information

• Chemical Name: C₆₇H₈₃N₃O₄S₄Si
• CAS No.: 1436577-51-3
• Molecular Formula: C₆₇H₈₃N₃O₄S₄Si
• Molecular Weight: 1150.76
• Mol file: 1436577-51-3.mol

Synonyms:C₆₇H₈₃N₃O₄S₄Si

Chemical Property of C₆₇H₈₃N₃O₄S₄Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of C₆₇H₈₃N₃O₄S₄Si

There total 4 articles about C₆₇H₈₃N₃O₄S₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

2-cyano-3-[5’’’-(9-ethyl-9H-carbazol-3-yl)-3’,3’’,3’’’,4-tetrahexyl(2,2’:5’,2’’:5’’,2’’’-quaterthiophene)-5-yl]-2-propenoic acid (1037440-21-3) + para-aminophenyltrimethoxysilane (33976-43-1) → C67H83N3O4S4Si (1436577-51-3)

Guidance literature:

2-cyano-3-[5’’’-(9-ethyl-9H-carbazol-3-yl)-3’,3’’,3’’’,4-tetrahexyl(2,2’:5’,2’’:5’’,2’’’-quaterthiophene)-5-yl]-2-propenoic acid; With oxalyl dichloride; In chloroform; N,N-dimethyl-formamide; for 1h; Inert atmosphere;

para-aminophenyltrimethoxysilane; With N-ethyl-N,N-diisopropylamine; In chloroform; N,N-dimethyl-formamide; at 0 - 20 ℃; for 2h; Inert atmosphere;

DOI:10.1002/chem.201603059

Reference yield: 82.0%

→ C67H83N3O4S4Si (1436577-51-3)

Guidance literature:

With oxalyl dichloride; N,N-dimethyl-formamide; In chloroform; at 25 ℃; for 1h;

With N-ethyl-N,N-diisopropylamine; In chloroform; at 10 ℃; for 1h;

Reference yield:

2-cyano-3-[5’’’-(9-ethyl-9H-carbazol-3-yl)-3’,3’’,3’’’,4-tetrahexyl(2,2’:5’,2’’:5’’,2’’’-quaterthiophene)-5-yl]-2-propenoic acid (1037440-21-3) → C67H83N3O4S4Si (1436577-51-3)

Guidance literature:

Multi-step reaction with 2 steps

1: oxalyl dichloride; N,N-dimethyl-formamide / chloroform / 1 h / 20 °C / Inert atmosphere

2: N-ethyl-N,N-diisopropylamine / 1 h / 10 - 20 °C

With oxalyl dichloride; N-ethyl-N,N-diisopropylamine; N,N-dimethyl-formamide; In chloroform;

DOI:10.1039/c4cc02192d

upstream raw materials:

2-cyano-3-[5’’’-(9-ethyl-9H-carbazol-3-yl)-3’,3’’,3’’’,4-tetrahexyl(2,2’:5’,2’’:5’’,2’’’-quaterthiophene)-5-yl]-2-propenoic acid

para-aminophenyltrimethoxysilane