tert-butyl-[1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-enyloxy]-diphenyl-silane

Base Information

Chemical Name:tert-butyl-[1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-enyloxy]-diphenyl-silane
CAS No.:863972-73-0
Molecular Formula:C₂₅H₃₄O₃Si
Molecular Weight:410.629
Hs Code.:

<i>tert</i>-butyl-[1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-enyloxy]-diphenyl-silane

Synonyms:tert-butyl-[1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-enyloxy]-diphenyl-silane

Suppliers and Price of tert-butyl-[1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-enyloxy]-diphenyl-silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-butyl-[1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-enyloxy]-diphenyl-silane

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Technology Process of tert-butyl-[1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-enyloxy]-diphenyl-silane

There total 1 articles about tert-butyl-[1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-enyloxy]-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 400710-04-5
1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-ol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 863972-73-0
tert-butyl-[1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-enyloxy]-diphenyl-silane

Guidance literature:: With 1H-imidazole; dmap; In N,N-dimethyl-formamide; at 20 ℃; for 12h;
DOI:10.1016/j.tetlet.2005.06.070

Reference yield: 98.0%

: 863972-73-0
tert-butyl-[1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-enyloxy]-diphenyl-silane

: 863972-74-1
3-(tert-butyl-diphenyl-silanyloxy)-hex-5-ene-1,2-diol

Guidance literature:: With acetic acid; In water; at 20 ℃; for 12h;
DOI:10.1016/j.tetlet.2005.06.070

Reference yield:

: 863972-73-0
tert-butyl-[1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-enyloxy]-diphenyl-silane

: (Z)-(5R,6R,10S)-5,6-Bis-benzyloxy-10-[(S)-1-(2-methoxy-ethoxymethoxy)-heptyl]-3,4,5,6,9,10-hexahydro-oxecin-2-one

Guidance literature:: Multi-step reaction with 8 steps

1.1: 98 percent / AcOH / H₂O / 12 h / 20 °C

2.1: 85 percent / 2,4,6-collidine / CH₂Cl₂ / -78 °C

3.1: MsCl; Et₃N / CH₂Cl₂ / 0 °C

3.2: 70 percent / K₂CO₃ / methanol / 20 °C

4.1: 70 percent / CuI / tetrahydrofuran / -23 °C

5.1: 80 percent / DIPEA / CH₂Cl₂

6.1: 90 percent / TBAF / tetrahydrofuran / 24 h / 20 °C

7.1: 80 percent / DCC; DMAP / CH₂Cl₂ / 12 h / 20 °C

8.1: (PCy₃)2Ru(Cl)2=CHPh / CH₂Cl₂ / 28 h / Heating

With 2,4,6-trimethyl-pyridine; dmap; copper(l) iodide; tetrabutyl ammonium fluoride; acetic acid; methanesulfonyl chloride; triethylamine; N-ethyl-N,N-diisopropylamine; dicyclohexyl-carbodiimide; Grubbs catalyst first generation; In tetrahydrofuran; dichloromethane; water;
DOI:10.1016/j.tetlet.2005.06.070