Formic acid (2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-iodomethyl-tetrahydro-pyran-3-yl ester

Base Information

Chemical Name:Formic acid (2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-iodomethyl-tetrahydro-pyran-3-yl ester
CAS No.:190511-66-1
Molecular Formula:C₂₉H₃₁IO₆
Molecular Weight:602.466
Hs Code.:

Synonyms:Formic acid (2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-iodomethyl-tetrahydro-pyran-3-yl ester

Suppliers and Price of Formic acid (2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-iodomethyl-tetrahydro-pyran-3-yl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Formic acid (2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-iodomethyl-tetrahydro-pyran-3-yl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Formic acid (2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-iodomethyl-tetrahydro-pyran-3-yl ester

There total 3 articles about Formic acid (2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-iodomethyl-tetrahydro-pyran-3-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 190511-65-0
(3aR,5R,6R,7S,7aS)-6,7-Bis-benzyloxy-5-benzyloxymethyl-hexahydro-furo[3,2-b]pyran-2-ol

: 190511-66-1
Formic acid (2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-iodomethyl-tetrahydro-pyran-3-yl ester

Guidance literature:: With [bis(acetoxy)iodo]benzene; iodine; In cyclohexane; benzene; Irradiation;
DOI:10.1016/S0040-4039(97)00576-5

Reference yield:

: 190511-64-9
(3aR,5R,6R,7S,7aS)-6,7-Bis-benzyloxy-5-benzyloxymethyl-hexahydro-furo[3,2-b]pyran-2-one

: 190511-66-1
Formic acid (2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-iodomethyl-tetrahydro-pyran-3-yl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / diisobutylaluminum hydride / CH₂Cl₂ / -78 °C

2: 90 percent / I₂, PhI(OAc₂)2 / benzene; cyclohexane / Irradiation

With [bis(acetoxy)iodo]benzene; iodine; diisobutylaluminium hydride; In dichloromethane; cyclohexane; benzene;
DOI:10.1016/S0040-4039(97)00576-5

Reference yield:

: 190511-63-8
(5R,6R,7S)-6,7-Bis-benzyloxy-5-benzyloxymethyl-3,3-dichloro-hexahydro-furo[3,2-b]pyran-2-one

: 190511-66-1
Formic acid (2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-iodomethyl-tetrahydro-pyran-3-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1: Zn / acetic acid / 80 °C

2: 85 percent / diisobutylaluminum hydride / CH₂Cl₂ / -78 °C

3: 90 percent / I₂, PhI(OAc₂)2 / benzene; cyclohexane / Irradiation

With [bis(acetoxy)iodo]benzene; iodine; diisobutylaluminium hydride; zinc; In dichloromethane; cyclohexane; acetic acid; benzene;
DOI:10.1016/S0040-4039(97)00576-5