o-cymantrenylcarbonylbenzoic acid

Base Information

• Chemical Name: o-cymantrenylcarbonylbenzoic acid
• CAS No.: 1224100-76-8
• Molecular Formula: C₁₆H₉MnO₆
• Molecular Weight: 352.182
• Mol file: 1224100-76-8.mol

Synonyms:o-cymantrenylcarbonylbenzoic acid

Chemical Property of o-cymantrenylcarbonylbenzoic acid

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of o-cymantrenylcarbonylbenzoic acid

There total 1 articles about o-cymantrenylcarbonylbenzoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

phthalic anhydride (85-44-9) + cymantrene (12079-65-1) → o-cymantrenylcarbonylbenzoic acid (1224100-76-8)

Guidance literature:

phthalic anhydride; With aluminum (III) chloride; In dichloromethane; for 0.5h; Inert atmosphere; Schlenk technique; Cooling with ice;

cymantrene; for 4.5h; Inert atmosphere; Schlenk technique; Reflux;

With hydrogenchloride; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.poly.2019.04.048

Reference yield: 81.0%

o-cymantrenylcarbonylbenzoic acid (1224100-76-8) + carbonic acid dimethyl ester (616-38-6) → methyl o-cymantrenylcarbonylbenzoate

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; for 13h; Reflux;

DOI:10.1016/j.poly.2019.04.048

Reference yield:

o-cymantrenylcarbonylbenzoic acid (1224100-76-8) → Mn(CO)3(C5H4CO(1,2-C6H4)COGLRKRLRKFRNKIKEK)

Guidance literature:

With 1-hydroxybenzotriazole; N,N-diisopropylcarbodiimide; CF₃COOH; In not given; treatment of GLRKRKRKFRNKIKEK peptide linked to polystyrene with cymantrene deriv. in presence of 5 equiv. of hydroxybenzotriazole/diimide deriv., treatment with trifluoroacetic acid in presence of different compds.; ppn. with diethyl ether at 0°C, MALDI and ESI-MS;

DOI:10.1039/b916907e

upstream raw materials:

phthalic anhydride

cymantrene