methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-((ethoxycarbonyl)methyl)-3-C-((Z)-(ethoxycarbonyl)methylene)-α-D-ribo-hexopyranoside

Base Information

Chemical Name:methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-((ethoxycarbonyl)methyl)-3-C-((Z)-(ethoxycarbonyl)methylene)-α-D-ribo-hexopyranoside
CAS No.:101199-49-9
Molecular Formula:C₂₂H₂₈O₈
Molecular Weight:420.46
Hs Code.:

Synonyms:methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-((ethoxycarbonyl)methyl)-3-C-((Z)-(ethoxycarbonyl)methylene)-α-D-ribo-hexopyranoside

Suppliers and Price of methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-((ethoxycarbonyl)methyl)-3-C-((Z)-(ethoxycarbonyl)methylene)-α-D-ribo-hexopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-((ethoxycarbonyl)methyl)-3-C-((Z)-(ethoxycarbonyl)methylene)-α-D-ribo-hexopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-((ethoxycarbonyl)methyl)-3-C-((Z)-(ethoxycarbonyl)methylene)-α-D-ribo-hexopyranoside

There total 2 articles about methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-((ethoxycarbonyl)methyl)-3-C-((Z)-(ethoxycarbonyl)methylene)-α-D-ribo-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 122672-65-5
methyl 2-deoxy-2-(2-ethoxy-2-oxoethyl)-4,6-O-(phenylmethylene)-α-D-ribohexopyranosid-3-ulose

: 1099-45-2
ethyl (triphenylphosphoranylidene)acetate

: 101199-49-9
methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-((ethoxycarbonyl)methyl)-3-C-((Z)-(ethoxycarbonyl)methylene)-α-D-ribo-hexopyranoside

Guidance literature:: In acetonitrile; for 72h; Heating;
DOI:10.1021/jo00283a033

Reference yield:

: 194149-26-3
methyl 2,3:4,6-di-O-benzylidene-α-D-mannopyranoside

: 101199-49-9
methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-((ethoxycarbonyl)methyl)-3-C-((Z)-(ethoxycarbonyl)methylene)-α-D-ribo-hexopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) n-BuLi, 2.) hexamethylphosphoramide / 1.) THF, from -40 deg C to -30 deg C, 30 min, 2.) THF, from -35 deg C to -30 deg C

2: 98 percent / acetonitrile / 72 h / Heating

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; In acetonitrile;
DOI:10.1021/jo00283a033