Acetic acid (1S,2R)-2-(diethoxy-phosphorylmethyl)-cyclohexylmethyl ester

Base Information

Chemical Name:Acetic acid (1S,2R)-2-(diethoxy-phosphorylmethyl)-cyclohexylmethyl ester
CAS No.:174152-14-8
Molecular Formula:C₁₄H₂₇O₅P
Molecular Weight:306.339
Hs Code.:

Synonyms:Acetic acid (1S,2R)-2-(diethoxy-phosphorylmethyl)-cyclohexylmethyl ester

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Chemical Property of Acetic acid (1S,2R)-2-(diethoxy-phosphorylmethyl)-cyclohexylmethyl ester

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Technology Process of Acetic acid (1S,2R)-2-(diethoxy-phosphorylmethyl)-cyclohexylmethyl ester

There total 9 articles about Acetic acid (1S,2R)-2-(diethoxy-phosphorylmethyl)-cyclohexylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 174152-17-1
Acetic acid (1S,6R)-6-(diethoxy-phosphorylmethyl)-cyclohex-3-enylmethyl ester

: 174152-14-8
Acetic acid (1S,2R)-2-(diethoxy-phosphorylmethyl)-cyclohexylmethyl ester

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethanol; for 10h; under 2942.03 Torr; Yield given;
DOI:10.1016/0957-4166(95)00403-3

Reference yield:

: 439919-46-7
cis-1,6-dihydroxymethyl-3-cyclohexene

: 174152-14-8
Acetic acid (1S,2R)-2-(diethoxy-phosphorylmethyl)-cyclohexylmethyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 12 h / 37 °C / Pseudomonas cepacia lipase

2: DMSO, (COCl)2, Et₃N / CH₂Cl₂ / -78 °C

3: Ti(OiPr)4 / toluene / 24 h / 0 °C

4: 70 percent / CH₂Cl₂ / 10 h / Heating

5: 80 percent / n-Bu₄SnH / toluene / 15 h / Heating

6: H₂ / 10percent Pd/C / ethanol / 10 h / 2942.03 Torr

With titanium(IV) isopropylate; oxalyl dichloride; n-Bu₄SnH; hydrogen; dimethyl sulfoxide; triethylamine; palladium on activated charcoal; In ethanol; dichloromethane; toluene;
DOI:10.1016/0957-4166(95)00403-3

Reference yield:

: 98516-11-1,118014-45-2,98516-10-0
acetic acid (1S,6R)-6-hydroxymethyl-cyclohex-3-enylmethyl ester

: 174152-14-8
Acetic acid (1S,2R)-2-(diethoxy-phosphorylmethyl)-cyclohexylmethyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: DMSO, (COCl)2, Et₃N / CH₂Cl₂ / -78 °C

2: Ti(OiPr)4 / toluene / 24 h / 0 °C

3: 70 percent / CH₂Cl₂ / 10 h / Heating

4: 80 percent / n-Bu₄SnH / toluene / 15 h / Heating

5: H₂ / 10percent Pd/C / ethanol / 10 h / 2942.03 Torr

With titanium(IV) isopropylate; oxalyl dichloride; n-Bu₄SnH; hydrogen; dimethyl sulfoxide; triethylamine; palladium on activated charcoal; In ethanol; dichloromethane; toluene;
DOI:10.1016/0957-4166(95)00403-3