4-acetamido-1,6-di-O-acetyl-2,4-dideoxy-3-O-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl)-5a-carba-β-L-lyxo-hexopyranose

Base Information

Chemical Name:4-acetamido-1,6-di-O-acetyl-2,4-dideoxy-3-O-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl)-5a-carba-β-L-lyxo-hexopyranose
CAS No.:153946-34-0
Molecular Formula:C₂₇H₃₉NO₁₅
Molecular Weight:617.604
Hs Code.:

Synonyms:4-acetamido-1,6-di-O-acetyl-2,4-dideoxy-3-O-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl)-5a-carba-β-L-lyxo-hexopyranose

Suppliers and Price of 4-acetamido-1,6-di-O-acetyl-2,4-dideoxy-3-O-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl)-5a-carba-β-L-lyxo-hexopyranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4-acetamido-1,6-di-O-acetyl-2,4-dideoxy-3-O-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl)-5a-carba-β-L-lyxo-hexopyranose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4-acetamido-1,6-di-O-acetyl-2,4-dideoxy-3-O-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl)-5a-carba-β-L-lyxo-hexopyranose

There total 9 articles about 4-acetamido-1,6-di-O-acetyl-2,4-dideoxy-3-O-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl)-5a-carba-β-L-lyxo-hexopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 104629-48-3
(1R,2R,3S)-5-oxo-3-<(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxy>cyclohexane-1,2-dicarboxylic anhydride

: 153946-34-0
4-acetamido-1,6-di-O-acetyl-2,4-dideoxy-3-O-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl)-5a-carba-β-L-lyxo-hexopyranose

Guidance literature:: Multi-step reaction with 6 steps

1: 70 percent / NaCNBH₃ / acetic acid

2: (COCl)2 / dimethylformamide; CH₂Cl₂

3: NaN₃ / tetrahydrofuran

4: 98 percent / benzene / 2 h / Heating

5: 35 percent / NEt₃, water / tetrahydrofuran

6: 1.) LiAlH₄; 2.) pyridine / 1.) THF, reflux; 2.) DMAP

With pyridine; lithium aluminium tetrahydride; sodium azide; oxalyl dichloride; water; sodium cyanoborohydride; triethylamine; In tetrahydrofuran; dichloromethane; acetic acid; N,N-dimethyl-formamide; benzene;
DOI:10.1016/S0040-4039(00)61476-4

Reference yield:

: 104629-46-1
(1R,2R,3S)-3-<(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxy>-8-trimethylsilyloxycyclohex-4-ene-1,2-dicarboxylic anhydride

: 153946-34-0
4-acetamido-1,6-di-O-acetyl-2,4-dideoxy-3-O-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl)-5a-carba-β-L-lyxo-hexopyranose

Guidance literature:: Multi-step reaction with 7 steps

1: concd. HCl / CHCl₃

2: 70 percent / NaCNBH₃ / acetic acid

3: (COCl)2 / dimethylformamide; CH₂Cl₂

4: NaN₃ / tetrahydrofuran

5: 98 percent / benzene / 2 h / Heating

6: 35 percent / NEt₃, water / tetrahydrofuran

7: 1.) LiAlH₄; 2.) pyridine / 1.) THF, reflux; 2.) DMAP

With pyridine; hydrogenchloride; lithium aluminium tetrahydride; sodium azide; oxalyl dichloride; water; sodium cyanoborohydride; triethylamine; In tetrahydrofuran; dichloromethane; chloroform; acetic acid; N,N-dimethyl-formamide; benzene;
DOI:10.1016/S0040-4039(00)61476-4

Reference yield:

: Acetic acid (2R,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-2-((1R,2R,3S,5S)-2-chlorocarbonyl-7-oxo-6-oxa-bicyclo[3.2.1]oct-3-yloxy)-tetrahydro-pyran-3-yl ester

: 153946-34-0
4-acetamido-1,6-di-O-acetyl-2,4-dideoxy-3-O-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl)-5a-carba-β-L-lyxo-hexopyranose

Guidance literature:: Multi-step reaction with 4 steps

1: NaN₃ / tetrahydrofuran

2: 98 percent / benzene / 2 h / Heating

3: 35 percent / NEt₃, water / tetrahydrofuran

4: 1.) LiAlH₄; 2.) pyridine / 1.) THF, reflux; 2.) DMAP

With pyridine; lithium aluminium tetrahydride; sodium azide; water; triethylamine; In tetrahydrofuran; benzene;
DOI:10.1016/S0040-4039(00)61476-4