Cyclopropanecarboxylic acid, 1-amino-2-(3-butenyl)-, methyl ester, (1R,2R)- (9CI)

Base Information

Chemical Name:Cyclopropanecarboxylic acid, 1-amino-2-(3-butenyl)-, methyl ester, (1R,2R)- (9CI)
CAS No.:770742-52-4
Molecular Formula:C₉H₁₅NO₂
Molecular Weight:169.224
Hs Code.:
Mol file:770742-52-4.mol

Synonyms:Cyclopropanecarboxylicacid, 1-amino-2-(3-butenyl)-, methyl ester, (1R,2R)- (9CI)

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Chemical Property of Cyclopropanecarboxylic acid, 1-amino-2-(3-butenyl)-, methyl ester, (1R,2R)- (9CI)

Chemical Property:

PSA：52.32000
LogP:1.54330

Purity/Quality:

Safty Information:

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Hazard Codes:

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Technology Process of Cyclopropanecarboxylic acid, 1-amino-2-(3-butenyl)-, methyl ester, (1R,2R)- (9CI)

There total 8 articles about Cyclopropanecarboxylic acid, 1-amino-2-(3-butenyl)-, methyl ester, (1R,2R)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (1S,2S)-2-But-3-enyl-1-(2-trimethylsilanyl-ethoxycarbonylamino)-cyclopropanecarboxylic acid tert-butyl ester

: 770742-52-4
methyl 1-amino-2-homoallylcyclopropyl carboxylate

Guidance literature:: With tetra(tert-butyl)-ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 16h;
DOI:10.1021/jo049288r

Reference yield:

: (1S,2S)-2-But-3-enyl-1-(2-trimethylsilanyl-ethoxycarbonylamino)-cyclopropanecarboxylic acid tert-butyl ester

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 770742-52-4
methyl 1-amino-2-homoallylcyclopropyl carboxylate

Guidance literature:: (1S,2S)-2-But-3-enyl-1-(2-trimethylsilanyl-ethoxycarbonylamino)-cyclopropanecarboxylic acid tert-butyl ester; With trifluoroacetic acid; In dichloromethane; at 20 ℃; for 16h;

diazomethane; In dichloromethane;
DOI:10.1021/jo049288r

Reference yield:

: 300830-80-2
2-but-3-enyl-cyclopropane-1,1-dicarboxylic acid tert-butyl ester

: 770742-52-4
methyl 1-amino-2-homoallylcyclopropyl carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: (PhO)2P(O)N₃; Et₃N / benzene / 3.5 h / Heating

1.2: 88 percent / benzene / 4 h / Heating

2.1: t-Bu₄NF / tetrahydrofuran / 16 h / 20 °C

With diphenyl phosphoryl azide; tetra(tert-butyl)-ammonium fluoride; triethylamine; In tetrahydrofuran; benzene;
DOI:10.1021/jo049288r