chloro(dioxygen)(η5-pentamethylcyclopentadienyl)(triphenylphosphine)ruthenium(IV)

Base Information

Chemical Name:chloro(dioxygen)(η5-pentamethylcyclopentadienyl)(triphenylphosphine)ruthenium(IV)
CAS No.:505093-99-2
Molecular Formula:C₂₈H₃₀ClO₂PRu
Molecular Weight:566.042
Hs Code.:

Synonyms:chloro(dioxygen)(η5-pentamethylcyclopentadienyl)(triphenylphosphine)ruthenium(IV)

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Chemical Property of chloro(dioxygen)(η5-pentamethylcyclopentadienyl)(triphenylphosphine)ruthenium(IV)

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Technology Process of chloro(dioxygen)(η5-pentamethylcyclopentadienyl)(triphenylphosphine)ruthenium(IV)

There total 2 articles about chloro(dioxygen)(η5-pentamethylcyclopentadienyl)(triphenylphosphine)ruthenium(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 92361-49-4
pentamethylcyclopentadienyl bis(triphenylphosphine)ruthenium(II) chloride

: 505093-99-2
chloro(dioxygen)(η5-pentamethylcyclopentadienyl)(triphenylphosphine)ruthenium(IV)

Guidance literature:: With air; In dichloromethane; byproducts: PPh3; Schlenk technique; soln. of Ru complex in CH2Cl2 was bubbled with air and stirred for 60 min; concd.; hexane added; filtered;
DOI:10.1016/S0022-328X(02)01978-2

Reference yield: 71.0%

: 92361-49-4
pentamethylcyclopentadienyl bis(triphenylphosphine)ruthenium(II) chloride

: 80937-33-3
oxygen

: 505093-99-2
chloro(dioxygen)(η5-pentamethylcyclopentadienyl)(triphenylphosphine)ruthenium(IV)

Guidance literature:: In acetone; byproducts: PPh3; Schlenk technique; O2 was bubbled through soln. of Ru complex in acetoneduring 45 min; filtered; washed (acetone); dried (vac.); elem. anal.;
DOI:10.1016/S0022-328X(02)01978-2

Reference yield: 71.0%

: 505093-99-2
chloro(dioxygen)(η5-pentamethylcyclopentadienyl)(triphenylphosphine)ruthenium(IV)

: 41821-91-4
axial-2-methoxy-4,6-dimethyl-1,3,2-λ3-dioxaphosphorinane

: 505094-01-9
chloro-bis-(2-methoxy-4,6-dimethyl-1,3,2-λ3-dioxaphosphorinane)(η5-pentamethylcyclopentadienyl)ruthenium(II)

: 505094-00-8
chloro(2-methoxy-4,6-dimethyl-1,3,2-λ3-dioxaphosphorinane)(η5-pentamethylcyclopentadienyl)(triphenylphosphine)ruthenium(II)

Guidance literature:: In tetrahydrofuran; (N2); Schlenk technique; ligand was added to soln. of Ru complex in THF at room temp.; soln. was refluxed for 15 min; mixt. was stirred at room temp. for 1 h; filtered; evapd. (vac.); fraction sol. in Et2O chromd. (silica, Et2O/hexane, 2/8); recrystd. (pentane, room temp.); elem. anal.;
DOI:10.1016/S0022-328X(02)01978-2