2-((1S,2S,5S)-2-Isopropenyl-5-methyl-cyclohexyl)-1,3-bis-methoxymethoxy-5-((E)-styryl)-benzene

Base Information

Chemical Name:2-((1S,2S,5S)-2-Isopropenyl-5-methyl-cyclohexyl)-1,3-bis-methoxymethoxy-5-((E)-styryl)-benzene
CAS No.:925977-58-8
Molecular Formula:C₂₈H₃₆O₄
Molecular Weight:436.591
Hs Code.:

Synonyms:2-((1S,2S,5S)-2-Isopropenyl-5-methyl-cyclohexyl)-1,3-bis-methoxymethoxy-5-((E)-styryl)-benzene

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Chemical Property of 2-((1S,2S,5S)-2-Isopropenyl-5-methyl-cyclohexyl)-1,3-bis-methoxymethoxy-5-((E)-styryl)-benzene

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Technology Process of 2-((1S,2S,5S)-2-Isopropenyl-5-methyl-cyclohexyl)-1,3-bis-methoxymethoxy-5-((E)-styryl)-benzene

There total 10 articles about 2-((1S,2S,5S)-2-Isopropenyl-5-methyl-cyclohexyl)-1,3-bis-methoxymethoxy-5-((E)-styryl)-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 925977-57-7
Methanesulfonic acid (1R,2R,4S,5S)-4-[2,6-bis-methoxymethoxy-4-((E)-styryl)-phenyl]-5-isopropenyl-2-methyl-cyclohexyl ester

: 925977-58-8
2-((1S,2S,5S)-2-Isopropenyl-5-methyl-cyclohexyl)-1,3-bis-methoxymethoxy-5-((E)-styryl)-benzene

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; for 8h; Heating;
DOI:10.1016/j.tet.2006.10.067

Reference yield:

: 903520-30-9
((1R,4S,6R)-4-Isopropenyl-1-methyl-7-oxa-bicyclo[4.1.0]hept-2-en-2-yloxy)-trimethyl-silane

: 925977-58-8
2-((1S,2S,5S)-2-Isopropenyl-5-methyl-cyclohexyl)-1,3-bis-methoxymethoxy-5-((E)-styryl)-benzene

Guidance literature:: Multi-step reaction with 9 steps

1.1: magnesium; 1,2-dibromoethane / tetrahydrofuran / 0.75 h / Heating

1.2: CuCN / tetrahydrofuran / -40 - 0 °C

1.3: tetrahydrofuran / 3 h / -10 - 0 °C

2.1: KF / methanol / 1 h / 20 °C

3.1: 93 percent / imidazole; DMAP / dimethylformamide / 3 h / 20 °C

4.1: 70 percent / lithium aluminum hydride / tetrahydrofuran / 1 h / -30 °C

5.1: NaH / tetrahydrofuran; various solvent(s) / 2 h / 50 °C

5.2: 93 percent / tetrahydrofuran / 5 h

6.1: 90 percent / AIBN; n-Bu₃SnH / toluene / 0.5 h / 90 °C

7.1: 98 percent / TBAF / tetrahydrofuran / 12 h / 20 °C

8.1: 97 percent / triethylamine / CH₂Cl₂ / 0.08 h / 0 °C

9.1: 80 percent / lithium aluminum hydride / diethyl ether / 8 h / Heating

With 1H-imidazole; dmap; potassium fluoride; lithium aluminium tetrahydride; 2,2'-azobis(isobutyronitrile); tetrabutyl ammonium fluoride; tri-n-butyl-tin hydride; sodium hydride; magnesium; ethylene dibromide; triethylamine; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide; toluene; 6.1: Barton radical deoxygenation;
DOI:10.1016/j.tet.2006.10.067

Reference yield:

: 2-Bromo-1,3-bis-methoxymethoxy-5-((E)-styryl)-benzene

: 925977-58-8
2-((1S,2S,5S)-2-Isopropenyl-5-methyl-cyclohexyl)-1,3-bis-methoxymethoxy-5-((E)-styryl)-benzene

Guidance literature:: Multi-step reaction with 9 steps

1.1: magnesium; 1,2-dibromoethane / tetrahydrofuran / 0.75 h / Heating

1.2: CuCN / tetrahydrofuran / -40 - 0 °C

1.3: tetrahydrofuran / 3 h / -10 - 0 °C

2.1: KF / methanol / 1 h / 20 °C

3.1: 93 percent / imidazole; DMAP / dimethylformamide / 3 h / 20 °C

4.1: 70 percent / lithium aluminum hydride / tetrahydrofuran / 1 h / -30 °C

5.1: NaH / tetrahydrofuran; various solvent(s) / 2 h / 50 °C

5.2: 93 percent / tetrahydrofuran / 5 h

6.1: 90 percent / AIBN; n-Bu₃SnH / toluene / 0.5 h / 90 °C

7.1: 98 percent / TBAF / tetrahydrofuran / 12 h / 20 °C

8.1: 97 percent / triethylamine / CH₂Cl₂ / 0.08 h / 0 °C

9.1: 80 percent / lithium aluminum hydride / diethyl ether / 8 h / Heating

With 1H-imidazole; dmap; potassium fluoride; lithium aluminium tetrahydride; 2,2'-azobis(isobutyronitrile); tetrabutyl ammonium fluoride; tri-n-butyl-tin hydride; sodium hydride; magnesium; ethylene dibromide; triethylamine; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide; toluene; 6.1: Barton radical deoxygenation;
DOI:10.1016/j.tet.2006.10.067