1 1'-BIS(PHENYLPHOSPHINIDENE)FERROCENE

Base Information

Chemical Name:1 1'-BIS(PHENYLPHOSPHINIDENE)FERROCENE
CAS No.:72954-06-4
Molecular Formula:C₁₆H₁₃P*Fe
Molecular Weight:292.1
Hs Code.:
Mol file:72954-06-4.mol

Synonyms:(1,1'-Ferrocenediyl)phenylphosphine;1,1'-Bis(phenylphosphinidene)ferrocene

Suppliers and Price of 1 1'-BIS(PHENYLPHOSPHINIDENE)FERROCENE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
1,1'-BIS(PHENYLPHOSPHINIDENE)FERROCENE 97.00%
1G
$ 744.02

Sigma-Aldrich
1,1′-Bis(phenylphosphinidene)ferrocene 97%
1g
$ 160.00

Total 6 raw suppliers

Chemical Property of 1 1'-BIS(PHENYLPHOSPHINIDENE)FERROCENE

Chemical Property:

Melting Point:88-92 °C(lit.)
Boiling Point:373.7oC at 760 mmHg
Flash Point:189.2oC
PSA：13.59000
LogP:4.10730
Storage Temp.:2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,1'-BIS(PHENYLPHOSPHINIDENE)FERROCENE 97.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses Reactant for:Preparation of macrocyclic tridentate ferrocenylphosphine ligandsPreparation of phosphorus-bridged ferrocenophane with syn and anti conformationsReaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenesRing-opening reactions via ring slippagePreparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate

Technology Process of 1 1'-BIS(PHENYLPHOSPHINIDENE)FERROCENE

There total 1 articles about 1 1'-BIS(PHENYLPHOSPHINIDENE)FERROCENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 1,1'-(ferrocenediyl)phenylphosphine

: 72954-06-4
poly(ferrocenylphenylphosphine)

Guidance literature:: In neat (no solvent); sealed Pyrex tube (vac., 0.01 mmHg); 120°C (1 h), 130°C (15 min); THF addn., filtering, concg., pptn. on hexanes addn.;
DOI:10.1021/om00012a017

Reference yield: 95.0%

: 10544-50-0
sulfur

: 72954-06-4
poly(ferrocenylphenylphosphine)

: 72954-09-7
Fe⁽²⁺⁾*C₆H₅P(S)(C₅H₄)2^(2-)=Fe(C₆H₅P(S)(C₅H₄)2)

Guidance literature:: In dichloromethane; N2-atmosphere; elem. anal.;
DOI:10.1021/om00012a017

Reference yield: 82.0%

: 72954-06-4
poly(ferrocenylphenylphosphine)

: 7553-56-2,12190-71-5,8031-47-8
iodine

: Fe⁽²⁺⁾*(C₆H₅)PI(C₅H₄)2^(1-)*I^(1-)*I*0.17C₆H₆=(C₆H₅)PI(C₅H₄)Fe(C₅H₄)I₂*0.17C₆H₆

Guidance literature:: In benzene; soln. I2 in benzene was added dropwise to soln. (PhPFc)n in benzene (1.5:1) at room temp. and stirred for 20 min; ppt. was washed with benzene and dried under vac.; elem. anal.;
DOI:10.1021/ic991147y