methyl 4,6-O-benzylidene-2-deoxy-2-C-(3-trimethylsilylprop-2-ynyl)-α-D-altroside

Base Information

Chemical Name:methyl 4,6-O-benzylidene-2-deoxy-2-C-(3-trimethylsilylprop-2-ynyl)-α-D-altroside
CAS No.:131529-36-7
Molecular Formula:C₂₀H₂₈O₅Si
Molecular Weight:376.525
Hs Code.:

Synonyms:methyl 4,6-O-benzylidene-2-deoxy-2-C-(3-trimethylsilylprop-2-ynyl)-α-D-altroside

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Chemical Property of methyl 4,6-O-benzylidene-2-deoxy-2-C-(3-trimethylsilylprop-2-ynyl)-α-D-altroside

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Technology Process of methyl 4,6-O-benzylidene-2-deoxy-2-C-(3-trimethylsilylprop-2-ynyl)-α-D-altroside

There total 4 articles about methyl 4,6-O-benzylidene-2-deoxy-2-C-(3-trimethylsilylprop-2-ynyl)-α-D-altroside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 131529-40-3
(2R,4aR,6S,7S,8S,8aR)-6-Methoxy-2-phenyl-8-trimethylsilanyloxy-7-(3-trimethylsilanyl-prop-2-ynyl)-hexahydro-pyrano[3,2-d][1,3]dioxine

: 131529-36-7
methyl 4,6-O-benzylidene-2-deoxy-2-C-(3-trimethylsilylprop-2-ynyl)-α-D-altroside

Guidance literature:: With camphor-10-sulfonic acid; In tetrahydrofuran; water;
DOI:10.1071/CH9901681

Reference yield:

: 66537-92-6
methyl 2,3-anhydro-4,6-benzylidene-α-D-allopyranoside

: 131529-36-7
methyl 4,6-O-benzylidene-2-deoxy-2-C-(3-trimethylsilylprop-2-ynyl)-α-D-altroside

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) BuLi / 1.) THF, hexane, 30 min, 2.) RT, 2.5 h

2: 1.) BuLi / 1.) THF, 30 min, 2.) 1 h

3: 94 percent / camphorsulfonic acid / tetrahydrofuran; H₂O

With n-butyllithium; camphor-10-sulfonic acid; In tetrahydrofuran; water;
DOI:10.1071/CH9901681

Reference yield:

: 131529-37-8
methyl 4,6-O-benzylidene-2-deoxy-2-C-(prop-2-ynyl)-α-D-altroside

: 131529-36-7
methyl 4,6-O-benzylidene-2-deoxy-2-C-(3-trimethylsilylprop-2-ynyl)-α-D-altroside

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) BuLi / 1.) THF, 30 min, 2.) 1 h

2: 94 percent / camphorsulfonic acid / tetrahydrofuran; H₂O

With n-butyllithium; camphor-10-sulfonic acid; In tetrahydrofuran; water;
DOI:10.1071/CH9901681