(2R,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylundecane

Base Information

Chemical Name:(2R,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylundecane
CAS No.:364597-64-8
Molecular Formula:C₃₅H₄₈O₃Si
Molecular Weight:544.85
Hs Code.:

Synonyms:(2R,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylundecane

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Chemical Property of (2R,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylundecane

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Technology Process of (2R,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylundecane

There total 7 articles about (2R,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylundecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 364597-63-7
(2R,3S,4S,6R,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methyl-4-(phenylseleno)undecane

: 364597-64-8
(2R,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylundecane

Guidance literature:: With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile);
DOI:10.1016/S0040-4039(01)00921-2

Reference yield:

: 364597-58-0
(3S)-3-{[tert-butyl(diphenyl)silyl]oxy}hexanal

: 364597-64-8
(2R,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylundecane

Guidance literature:: Multi-step reaction with 5 steps

1: SnCl₄

2: 68 percent / Ph₃P; DEAD

3: 94 percent / NaOH

4: 60 percent / SnCl₄

5: 89 percent / Bu₃SnH / AIBN

With sodium hydroxide; tri-n-butyl-tin hydride; tin(IV) chloride; triphenylphosphine; diethylazodicarboxylate; 2,2'-azobis(isobutyronitrile); 2: Mitsunobu inversion / 3: saponification / 5: reduction;
DOI:10.1016/S0040-4039(01)00921-2

Reference yield:

: (4R)-5-benzyloxy-4-methylpent-2-enyl(tributyl)stannane

: 364597-64-8
(2R,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylundecane

Guidance literature:: Multi-step reaction with 5 steps

1: SnCl₄

2: 68 percent / Ph₃P; DEAD

3: 94 percent / NaOH

4: 60 percent / SnCl₄

5: 89 percent / Bu₃SnH / AIBN

With sodium hydroxide; tri-n-butyl-tin hydride; tin(IV) chloride; triphenylphosphine; diethylazodicarboxylate; 2,2'-azobis(isobutyronitrile); 2: Mitsunobu inversion / 3: saponification / 5: reduction;
DOI:10.1016/S0040-4039(01)00921-2