C₅₈H₈₂O₆SSi₂

Base Information

Chemical Name:C₅₈H₈₂O₆SSi₂
CAS No.:179815-60-2
Molecular Formula:C₅₈H₈₂O₆SSi₂
Molecular Weight:963.522
Hs Code.:

C<sub>58</sub>H<sub>82</sub>O<sub>6</sub>SSi<sub>2</sub>

Synonyms:C₅₈H₈₂O₆SSi₂

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Chemical Property of C₅₈H₈₂O₆SSi₂

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Technology Process of C₅₈H₈₂O₆SSi₂

There total 32 articles about C₅₈H₈₂O₆SSi₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 27607-77-8
trimethylsilyl trifluoromethanesulfonate

: 179815-59-9
C₅₅H₇₄O₆SSi

: 179815-60-2
C₅₈H₈₂O₆SSi₂

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane;
DOI:10.1021/ja961071u

Reference yield:

: 69143-05-1
(E)-4-methyl-pent-2-en-1-ol

: 179815-60-2
C₅₈H₈₂O₆SSi₂

Guidance literature:: Multi-step reaction with 26 steps

1: 74 percent / (-)-diethyl tartrate, Ti(i-Pr)4, t-BuOOH / CH₂Cl₂ / 20 h / -20 °C

2: 2.) NaIO₄ / 1.) Et₂O, 0 deg C, 3.5 h, 2.) H₂O, 16 h

3: 82 percent / pyridine, 4-(dimethylamino)pyridine / CH₂Cl₂ / 24 h / 0 - 20 °C

4: 92 percent / Et₃N, 4-(dimethylamino)pyridine / 8 h / Ambient temperature

5: 88 percent / NaI / butan-2-one / 4 h / Heating

6: 94 percent / LDA, hexamethylphosphoramide / tetrahydrofuran / 0.08 h

7: 1.) n-BuLi / 1.) THF, -78 deg C, 30 min, 2.) THF, -78 deg C, 1 h

8: 88 percent / K₂CO₃ / 16 h / Ambient temperature

9: TsOH / tetrahydrofuran; H₂O

10: 78 percent / <(n-Bu₃P)3CuI>4 / tetrahydrofuran / 0.5 h / -45 °C

11: 25 percent / NaBH₄ / 1,2-dimethoxy-ethane / 1 h

12: 1.) CrO₃, H₂SO₄, 2.) NaBH₄ / 1.) acetone, 10 min, 2.) DME, 1 h

13: 100 percent / imidazole, 4-(dimethylamino)pyridine / dimethylformamide / 60 h / 25 °C

14: 1.) 9-BBN, 2.) aq. H₂O₂, aq. NaOH / 1.) THF, irradiation, 1 h, 2.) THF, 3 h

15: 1.) (COCl)2, DMSO, 2.) Et₃N / 1.) CH₂Cl₂, -78 deg C, 15 min, 2.) CH₂Cl₂, -60 deg C, 5 min

16: 89 percent / CH₂Cl₂ / 16 h / Heating

17: 91 percent / i-Bu₂AlH / tetrahydrofuran / 0.67 h / -78 °C

18: methyltriphenoxyphosphonium iodide / dimethylformamide / 0.33 h / 25 °C

19: 1.) sodium hexamethyldisilazide / 1.) THF, -78 deg C, 1 h, 2.) THF, -78 deg C, 3 h

20: 77 percent / LiAlH₄ / diethyl ether / 2 h / -25 - 20 °C

21: 98 percent / methyltriphenoxyphosphonium iodide / dimethylformamide / 0.33 h / 25 °C

22: 100 percent / acetonitrile / 96 h / Heating

23: 1.) MeLi-LiBr / 1.) THF, -78 deg C, 2.) THF, -78 deg C, 3.5 h

24: I₂ / benzene / 2 h / 25 °C

25: 72 percent / K₂CO₃ / methanol

26: 87 percent / 2,6-lutidine / CH₂Cl₂

With pyridine; 1H-imidazole; 2,6-dimethylpyridine; chromium(VI) oxide; tert.-butylhydroperoxide; N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; sodium hydroxide; sodium tetrahydroborate; sodium periodate; lithium aluminium tetrahydride; 9-borabicyclo[3.3.1]nonane dimer; n-butyllithium; oxalyl dichloride; <(n-Bu3P)3CuI>4; sulfuric acid; methyltriphenoxyphosphonium iodide; methyllithium; dihydrogen peroxide; iodine; sodium hexamethyldisilazane; diisobutylaluminium hydride; potassium carbonate; toluene-4-sulfonic acid; isopropyl titanoate(IV); dimethyl sulfoxide; (-)-diethyl tartrate; triethylamine; sodium iodide; lithium bromide; lithium diisopropyl amide; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile; butanone; benzene;
DOI:10.1021/ja961071u

Reference yield:

: 15790-86-0
ethyl-4-methyl-2-(E)-penteneoate

: 179815-60-2
C₅₈H₈₂O₆SSi₂

Guidance literature:: Multi-step reaction with 27 steps

1: 97 percent / iBu₂AlH / tetrahydrofuran / -78 - 0 °C

2: 74 percent / (-)-diethyl tartrate, Ti(i-Pr)4, t-BuOOH / CH₂Cl₂ / 20 h / -20 °C

3: 2.) NaIO₄ / 1.) Et₂O, 0 deg C, 3.5 h, 2.) H₂O, 16 h

4: 82 percent / pyridine, 4-(dimethylamino)pyridine / CH₂Cl₂ / 24 h / 0 - 20 °C

5: 92 percent / Et₃N, 4-(dimethylamino)pyridine / 8 h / Ambient temperature

6: 88 percent / NaI / butan-2-one / 4 h / Heating

7: 94 percent / LDA, hexamethylphosphoramide / tetrahydrofuran / 0.08 h

8: 1.) n-BuLi / 1.) THF, -78 deg C, 30 min, 2.) THF, -78 deg C, 1 h

9: 88 percent / K₂CO₃ / 16 h / Ambient temperature

10: TsOH / tetrahydrofuran; H₂O

11: 78 percent / <(n-Bu₃P)3CuI>4 / tetrahydrofuran / 0.5 h / -45 °C

12: 25 percent / NaBH₄ / 1,2-dimethoxy-ethane / 1 h

13: 1.) CrO₃, H₂SO₄, 2.) NaBH₄ / 1.) acetone, 10 min, 2.) DME, 1 h

14: 100 percent / imidazole, 4-(dimethylamino)pyridine / dimethylformamide / 60 h / 25 °C

15: 1.) 9-BBN, 2.) aq. H₂O₂, aq. NaOH / 1.) THF, irradiation, 1 h, 2.) THF, 3 h

16: 1.) (COCl)2, DMSO, 2.) Et₃N / 1.) CH₂Cl₂, -78 deg C, 15 min, 2.) CH₂Cl₂, -60 deg C, 5 min

17: 89 percent / CH₂Cl₂ / 16 h / Heating

18: 91 percent / i-Bu₂AlH / tetrahydrofuran / 0.67 h / -78 °C

19: methyltriphenoxyphosphonium iodide / dimethylformamide / 0.33 h / 25 °C

20: 1.) sodium hexamethyldisilazide / 1.) THF, -78 deg C, 1 h, 2.) THF, -78 deg C, 3 h

21: 77 percent / LiAlH₄ / diethyl ether / 2 h / -25 - 20 °C

22: 98 percent / methyltriphenoxyphosphonium iodide / dimethylformamide / 0.33 h / 25 °C

23: 100 percent / acetonitrile / 96 h / Heating

24: 1.) MeLi-LiBr / 1.) THF, -78 deg C, 2.) THF, -78 deg C, 3.5 h

25: I₂ / benzene / 2 h / 25 °C

26: 72 percent / K₂CO₃ / methanol

27: 87 percent / 2,6-lutidine / CH₂Cl₂

With pyridine; 1H-imidazole; 2,6-dimethylpyridine; chromium(VI) oxide; tert.-butylhydroperoxide; N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; sodium hydroxide; sodium tetrahydroborate; sodium periodate; lithium aluminium tetrahydride; 9-borabicyclo[3.3.1]nonane dimer; n-butyllithium; oxalyl dichloride; <(n-Bu3P)3CuI>4; sulfuric acid; methyltriphenoxyphosphonium iodide; methyllithium; dihydrogen peroxide; iodine; sodium hexamethyldisilazane; diisobutylaluminium hydride; potassium carbonate; toluene-4-sulfonic acid; isopropyl titanoate(IV); dimethyl sulfoxide; (-)-diethyl tartrate; triethylamine; sodium iodide; lithium bromide; lithium diisopropyl amide; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile; butanone; benzene;
DOI:10.1021/ja961071u