3,4-di-O-[2-[(1S)-1-phenylethoxy]acetyl]-6-O-triisopropylsilyl-2-C-methyl-D-glucal

Base Information

Chemical Name:3,4-di-O-[2-[(1S)-1-phenylethoxy]acetyl]-6-O-triisopropylsilyl-2-C-methyl-D-glucal
CAS No.:287400-51-5
Molecular Formula:C₃₆H₅₂O₈Si
Molecular Weight:640.89
Hs Code.:

Synonyms:3,4-di-O-[2-[(1S)-1-phenylethoxy]acetyl]-6-O-triisopropylsilyl-2-C-methyl-D-glucal

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Chemical Property of 3,4-di-O-[2-[(1S)-1-phenylethoxy]acetyl]-6-O-triisopropylsilyl-2-C-methyl-D-glucal

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Technology Process of 3,4-di-O-[2-[(1S)-1-phenylethoxy]acetyl]-6-O-triisopropylsilyl-2-C-methyl-D-glucal

There total 9 articles about 3,4-di-O-[2-[(1S)-1-phenylethoxy]acetyl]-6-O-triisopropylsilyl-2-C-methyl-D-glucal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 287400-90-2
(S)-methylbenzyloxyacetic acid

: 287400-50-4
6-O-triisopropylsilyl-2-C-methyl-D-glucal

: 287400-51-5
3,4-di-O-[2-[(1S)-1-phenylethoxy]acetyl]-6-O-triisopropylsilyl-2-C-methyl-D-glucal

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; for 1.5h;
DOI:10.1021/jo0002801

Reference yield:

: 13154-24-0
triisopropylsilyl chloride

: 287400-51-5
3,4-di-O-[2-[(1S)-1-phenylethoxy]acetyl]-6-O-triisopropylsilyl-2-C-methyl-D-glucal

Guidance literature:: Multi-step reaction with 2 steps

1: 1.5815 g / imidazole / dimethylformamide / 0.33 h

2: 88 percent / DCC; DMAP / CH₂Cl₂ / 1.5 h

With 1H-imidazole; dmap; dicyclohexyl-carbodiimide; In dichloromethane; N,N-dimethyl-formamide; 1: silylation / 2: Condensation;
DOI:10.1021/jo0002801

Reference yield:

: 1445-91-6
(S)-1-phenylethanol

: 287400-51-5
3,4-di-O-[2-[(1S)-1-phenylethoxy]acetyl]-6-O-triisopropylsilyl-2-C-methyl-D-glucal

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / KH / tetrahydrofuran / 20 h / Heating

2: 88 percent / DCC; DMAP / CH₂Cl₂ / 1.5 h

With dmap; potassium hydride; dicyclohexyl-carbodiimide; In tetrahydrofuran; dichloromethane; 1: Alkylation / 2: Condensation;
DOI:10.1021/jo0002801