(1R,2R,5R)-5-Isopropenyl-2-methyl-1-(tert-butyldiphenylsilanyloxy)cyclohexane

Base Information

Chemical Name:(1R,2R,5R)-5-Isopropenyl-2-methyl-1-(tert-butyldiphenylsilanyloxy)cyclohexane
CAS No.:330798-45-3
Molecular Formula:C₂₆H₃₆OSi
Molecular Weight:392.657
Hs Code.:

Synonyms:(1R,2R,5R)-5-Isopropenyl-2-methyl-1-(tert-butyldiphenylsilanyloxy)cyclohexane

Suppliers and Price of (1R,2R,5R)-5-Isopropenyl-2-methyl-1-(tert-butyldiphenylsilanyloxy)cyclohexane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,2R,5R)-5-Isopropenyl-2-methyl-1-(tert-butyldiphenylsilanyloxy)cyclohexane

Chemical Property:

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Technology Process of (1R,2R,5R)-5-Isopropenyl-2-methyl-1-(tert-butyldiphenylsilanyloxy)cyclohexane

There total 1 articles about (1R,2R,5R)-5-Isopropenyl-2-methyl-1-(tert-butyldiphenylsilanyloxy)cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 619-01-2,18675-33-7,18675-34-8,18675-35-9,20549-48-8,22567-21-1,22567-22-2,36237-64-6,38049-26-2,51773-45-6,53796-77-3,53796-80-8,73804-29-2,20549-47-7,17699-09-1
(1R,2R,4R)-dihydrocarveol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 330798-45-3
(1R,2R,5R)-5-Isopropenyl-2-methyl-1-(tert-butyldiphenylsilanyloxy)cyclohexane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 2h;
DOI:10.1002/1521-3765(20010105)7:1<161::AID-CHEM161>3.0.CO;2-9

Reference yield: 93.0%

: 330798-45-3
(1R,2R,5R)-5-Isopropenyl-2-methyl-1-(tert-butyldiphenylsilanyloxy)cyclohexane

: 330798-46-4
(1'R,3'R,4'R)-1-{4'-Methylcyclohexyl-3'-(tert-butyldiphenylsilanyloxy)}ethanone

Guidance literature:: (1R,2R,5R)-5-Isopropenyl-2-methyl-1-(tert-butyldiphenylsilanyloxy)cyclohexane; With ozone; In methanol; dichloromethane; at -78 ℃;

With triphenylphosphine; In methanol; dichloromethane; at -78 - 20 ℃; Further stages.;
DOI:10.1002/1521-3765(20010105)7:1<161::AID-CHEM161>3.0.CO;2-9

Reference yield:

: 330798-45-3
(1R,2R,5R)-5-Isopropenyl-2-methyl-1-(tert-butyldiphenylsilanyloxy)cyclohexane

: (4R,1'R,2'R,1''R,3''R,4''R)-4-(2'-Trifluoroacetamido-1'-phenylpropoxy)-4-(3''-tert-butyldiphenylsilanyloxy-4''-methylcyclohexyl)pent-1-ene

Guidance literature:: Multi-step reaction with 2 steps

1.1: O₃ / CH₂Cl₂; methanol / -78 °C

1.2: 93 percent / PPh₃ / CH₂Cl₂; methanol / -78 - 20 °C

2.1: 64 percent / TfOH / CH₂Cl₂ / 72 h / -78 °C

With trifluorormethanesulfonic acid; ozone; In methanol; dichloromethane;
DOI:10.1002/1521-3765(20010105)7:1<161::AID-CHEM161>3.0.CO;2-9